Effects of sulfur poisoning on physicochemical properties and performance of MnO2/AlNi-PILC for toluene catalytic combustion

• Published in: Journal of hazardous materials 2022-08, Vol.435, p.128950-128950, Article 128950
• Main Authors: Wang, Zhuo, Xie, Kaiyuan, Jiang, Baishun, Zuo, Shufeng, Wang, Qiuyan
• Format: Article
• Language: English
• Subjects: In-situ sulfur poisoning; MnO2/AlNi-PILC; Structural changes; Toluene catalytic combustion
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2022.128950

AlNi pillared clay (AlNi-PILC) was synthesized firstly, and then MnO2 was supported via wetness impregnation from nitrate precursors. Sulphation was performed by in-situ decomposing ammonium sulfate with different concentrations over MnO2/AlNi-PILC. Catalysts before and after sulfur poisoning were characterized by XRD, N2 adsorption/desorption, HRTEM, XPS, H2-TPR and NH3-TPD. MnO2/AlNi-PILC exhibited high catalytic activity, allowing the complete toluene combustion. Structure of the catalyst was obviously damaged after sulfur poisoning. (001) crystal plane strength of AlNi-PILC was decreased significantly. Meanwhile, the specific surface area and pore volume reduced with increase of sulfate concentration. Sulfur species were readily formed on the surface of poisoned catalyst and deposited in the pore structure of AlNi-PILC, which resulted in significant impacts on the structural stability, acidity and the number of active species. These changes were responsible for the decreased catalytic performance. [Display omitted] •In-situ (NH4)2SO4 decomposition method was used to simulate sulfur poisoning.•Sulfur poisoning damaged the layer structure and (001) crystal plane of AlNi-PILC.•Sulfur poisoning reduced SBET, strong acid sites, redox property and Mn4+ content.•Deactivation of catalyst was attributed to inactive and stable sulfate species.