In Situ Prepared NRCPFs as Highly Active Photo Platforms for in Situ Bond Formation Between Aryldiazonium Salts and Heteroarenes

Covalent perylene frameworks (CPFs) with melamine linkages have newly received rising interest for a variety of applications because of nitrogen‐rich content and high stability. Herein, we account a new simple strategy to in situ attain nitrogen‐rich covalent perylene frameworks (NRCPFs) as highly a...

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Bibliographic Details
Published in:Photochemistry and photobiology 2022-07, Vol.98 (4), p.748-753
Main Authors: Singh, Satyam, Yadav, Rajesh Kumar, Kim, Tae Wu, Singh, Chandani, Singh, Pooja, Chaubey, Surabhi, Rose, Baimuratova, Gulzhian, Dzhardimalieva, Khare, Prateek
Format: Article
Language:English
Subjects:
Bonding
Hydrogen bonds
Melamine
Nitrogen
Platforms
Salts
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Summary:Covalent perylene frameworks (CPFs) with melamine linkages have newly received rising interest for a variety of applications because of nitrogen‐rich content and high stability. Herein, we account a new simple strategy to in situ attain nitrogen‐rich covalent perylene frameworks (NRCPFs) as highly active photo platforms for in situ bond formation between aryldiazonium salts and heteroarenes (C–H bond arylation) through the controlled photoredox route. C–H bond arylation between aryldiazonium salts and heteroarenes through in situ prepared NRCPFs photocatalyst under solar light irradiation. The NRCPFs photocatalyst has been more efficient due to the nitrogen enrich covalent perylene framework which is utilized for C–H bond arylation. C–H bond arylated products have a wide range of industrial and medicinal applications.
ISSN:0031-8655
1751-1097
DOI:10.1111/php.13639