Production of pyrolytic oil from ULDP plastics using silica-alumina catalyst and used as fuel for DI diesel engine

A rapid increase in the use of non-biodegradable plastics and their disposal after use has had a detrimental impact on the environment. Used plastics (used low-density polyethylene - ULDP) were selected as feedstock for the extraction of pyrolytic oil. The pyrolysis process was carried out in a semi...

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Bibliographic Details
Published in:RSC advances 2020-10, Vol.1 (61), p.37266-37279
Main Authors: Gopinath, Soundararajan, Devan, P. K, Pitchandi, K
Format: Article
Language:English
Subjects:
Aluminum oxide
Biodegradability
Biodegradable materials
Catalysts
Chemistry
Combustion
Diesel engines
Emission analysis
Environmental impact
Fluidizing
Heat release rate
Hexadecane
Low density polyethylenes
Mixtures
Nitrogen oxides
Nuclear fuels
Polymers
Pyrolysis
Silicon dioxide
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Summary:A rapid increase in the use of non-biodegradable plastics and their disposal after use has had a detrimental impact on the environment. Used plastics (used low-density polyethylene - ULDP) were selected as feedstock for the extraction of pyrolytic oil. The pyrolysis process was carried out in a semi-batch reactor with a silica alumina catalyst in the existence of fluidizing gas N 2 in a reactor at 500 °C for 60 min. The maximum liquid, gas, and char yields were 93.5 wt%, 5.4 wt%, and 1.1 wt%, respectively. Experimental analysis was carried out to obtain their functional and structural groups by FT-IR and the carbon distribution was identified by GC-MS analysis. The blends of 20%, 40%, 60%, 80%, and 100% on a volume basis were chosen for the detailed study. For the pyrolytic blends, the combustion, performance, and emission characteristics were tested at different engine loads. During combustion, the heat release rate was extremely high for neat ULDP oil because of the high energy content and a higher cetane index. The efficiency of ULDP20 was higher than in other blends, whereas NOx and smoke emissions of ULDP20 were lower among the blends but higher than diesel. ULDP20 performed similarly as diesel. Hence, ULDP20 is recommended as a fuel for the diesel engine. Lower acidity ratio of SA catalyst influences higher yield of ULDP oil and is suggested as a novel fuel for unmodified diesel engine.
ISSN:2046-2069
2046-2069
DOI:10.1039/d0ra07073d