Three-dimensional honeycomb-like porous carbon derived from corncob for the removal of heavy metals from water by capacitive deionization

• Published in: RSC advances 2018-01, Vol.8 (3), p.1159-1167
• Main Authors: Zhang, X. F, Wang, B, Yu, J, Wu, X. N, Zang, Y. H, Gao, H. C, Su, P. C, Hao, S. Q
• Format: Article
• Language: English
• Subjects: Aqueous solutions; Carbonization; Chemistry; Chromium; Deionization; Electrical resistivity; Electrode materials; Electrodes; Heavy metals; Honeycomb construction
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c7ra10689k

In this study, porous carbon (3DHPC) with a 3D honeycomb-like structure was synthesized from waste biomass corncob via hydrothermal carbonization coupled with KOH activation and investigated as a capacitive deionization (CDI) electrode material. The obtained 3DHPC possesses a hierarchal macroporous and mesoporous structure, and a large accessible specific surface area (952 m 2 g −1 ). Electrochemical tests showed that the 3DHPC electrode exhibited a specific capacitance of 452 F g −1 and good electric conductivity. Moreover, the feasibility of electrosorptive removal of chromium( vi ) from an aqueous solution using the 3DHPC electrode was demonstrated. When 1.0 V was applied to a solution containing 30 mg L −1 chromium( vi ), the 3DHPC electrode exhibited a higher removal efficiency of 91.58% compared with that in the open circuit condition. This enhanced adsorption results from the improved affinity between chromium( vi ) and the electrode under electrochemical assistance involving a non-faradic process. Consequently, the 3DHPC electrode with typical double-layer capacitor behavior is demonstrated to be a favorable electrode material for capacitive deionization. A porous carbon electrode with a 3D honeycomb-like structure demonstrates a high removal efficiency for the removal of chromium( vi ) from water.