Photocatalytic degradation of cefixime using visible light-driven Z-scheme ZnO nanorod/Zn2TiO4/GO heterostructure

• Published in: Journal of environmental management 2022-08, Vol.316, p.115195-115195, Article 115195
• Main Authors: Behineh, Elham Sadat, Solaimany Nazar, Ali Reza, Farhadian, Mehrdad, Moghadam, Majid
• Format: Article
• Language: English
• Subjects: Cefixime photocatalytic degradation; Novel Z-scheme; Zn2TiO4/GO; ZnO nanorod
• ISSN: 0301-4797; 1095-8630
• DOI: 10.1016/j.jenvman.2022.115195

ZnO nanorod along with a Zn2TiO4/GO heterostructure with enhanced charge transfer capability was synthesized by a facile sol-gel method. FT-IR, XRD, XPS, TEM, SEM, EDX, UV–Vis DRS, photocurrent response and PL analyses were applied to characterize the as-prepared photocatalysts. To investigate the photocatalytic activity of the composite, Cefixime (CEF) removal under visible light was evaluated. The ZnO nanorod/Zn2TiO4/GO, including 65 wt% ZnO and 3 wt% graphene oxide, showed the highest CEF degradation and was selected as the optimal ternary composite. Reduction of electron-hole pair recombination rate, successful interfacial charge transfers, and more visible light reception in the Z-scheme system were the important reasons for improving the photocatalytic properties of ZnO nanorod/Zn2TiO4/GO. Effective operating parameters in the CEF photocatalytic removal process were optimized employing the response surface method and were as follows: photocatalyst dosage = 0.88 g/L, pH = 5, radiation time = 115 min, and CEF concentration = 10 ppm. The photocatalytic degradation% of CEF and total organic carbon (TOC) removal% under the optimal conditions were 71.4 and 57.5%, respectively, for the three-component composite indicating the production of intermediate species during the process. This photocatalytic reaction confirmed the first-order kinetic and using the ZnO nanorod/Zn2TiO4/GO composite was able to improve the reaction rate by about 2.7 and 6.2 times more than ZnO nanorod/Zn2TiO4 and ZnO, respectively. The effects of radiation intensity and temperature were investigated and 175 W/m2 and 35 °C were obtained as optimum values. Eventually, according to the trapping test, h+, superoxide radical, and hydroxyl radical are the most effective active species in this photocatalytic reaction, respectively. [Display omitted] •The Z-scheme ZnO nanorod/Zn2TiO4/GO was synthesized via simple sol-gel method.•Enhanced Cefixime visible-light degradation using ZnO nanorod/Zn2TiO4/GO.•Graphene Oxide had a notable effect on the catalytic behavior of ZnO/Zn2TiO4 in visible light.•The effect of operational parameters in Cefixime photocatalytic degradation were performed.•h+, O2− ͦ were the most effective active species in Cefixime photodegradation.