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An electron-deficient MOF as an efficient electron-transfer catalyst for selective oxidative carbon-carbon coupling of 2,6-di- tert -butylphenol
Naphthalene diimides (NDIs), a type of electron-deficient dye molecule with high quadrupole moment and excellent redox activity, have been utilized in various fields, such as energy transfer, chemical sensing, anion transport, and photo-/electrochromic materials. In this study, an electron-deficient...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2022-05, Vol.51 (21), p.8234-8239 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c296t-d7bf96130768ca4b23006665865200856d8f0995fed4039559b6704386e19aa83 |
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| container_end_page | 8239 |
| container_issue | 21 |
| container_start_page | 8234 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Liu, Teng Shen, Xianfu Liu, Zhengfen Zhang, Feng Liu, Jian-Jun |
| description | Naphthalene diimides (NDIs), a type of electron-deficient dye molecule with high quadrupole moment and excellent redox activity, have been utilized in various fields, such as energy transfer, chemical sensing, anion transport, and photo-/electrochromic materials. In this study, an electron-deficient metal-organic framework with one-dimensional channels, Eu
(BBNDI)
(DMF)
(MOF 1) (H
BBNDI =
,
'-bis(3-benzoic acid)naphthalene diimide), was successfully constructed based on the naphthalene diimide derivative. Because of the generation of NDI radicals by electron transfer between components, this material exhibits fast-responsive reversible photochromic properties. Moreover, it shows high efficiency and selective oxidation of 2,6-di-
-butylphenol to its quinone derivative, aldehyde, and dimeric or trimeric phenol derivative by controlling the reaction conditions. |
| doi_str_mv | 10.1039/d2dt00869f |
| format | article |
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(BBNDI)
(DMF)
(MOF 1) (H
BBNDI =
,
'-bis(3-benzoic acid)naphthalene diimide), was successfully constructed based on the naphthalene diimide derivative. Because of the generation of NDI radicals by electron transfer between components, this material exhibits fast-responsive reversible photochromic properties. Moreover, it shows high efficiency and selective oxidation of 2,6-di-
-butylphenol to its quinone derivative, aldehyde, and dimeric or trimeric phenol derivative by controlling the reaction conditions.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt00869f</identifier><identifier>PMID: 35575225</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Aldehydes ; Benzoic acid ; Carbon ; Diimide ; Electrochromism ; Electron transfer ; Electrons ; Energy transfer ; Metal-organic frameworks ; Naphthalene ; Oxidation ; Quadrupoles ; Quinones</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-05, Vol.51 (21), p.8234-8239</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c296t-d7bf96130768ca4b23006665865200856d8f0995fed4039559b6704386e19aa83</citedby><cites>FETCH-LOGICAL-c296t-d7bf96130768ca4b23006665865200856d8f0995fed4039559b6704386e19aa83</cites><orcidid>0000-0002-7480-0444 ; 0000-0001-9912-5396</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35575225$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Teng</creatorcontrib><creatorcontrib>Shen, Xianfu</creatorcontrib><creatorcontrib>Liu, Zhengfen</creatorcontrib><creatorcontrib>Zhang, Feng</creatorcontrib><creatorcontrib>Liu, Jian-Jun</creatorcontrib><title>An electron-deficient MOF as an efficient electron-transfer catalyst for selective oxidative carbon-carbon coupling of 2,6-di- tert -butylphenol</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Naphthalene diimides (NDIs), a type of electron-deficient dye molecule with high quadrupole moment and excellent redox activity, have been utilized in various fields, such as energy transfer, chemical sensing, anion transport, and photo-/electrochromic materials. In this study, an electron-deficient metal-organic framework with one-dimensional channels, Eu
(BBNDI)
(DMF)
(MOF 1) (H
BBNDI =
,
'-bis(3-benzoic acid)naphthalene diimide), was successfully constructed based on the naphthalene diimide derivative. Because of the generation of NDI radicals by electron transfer between components, this material exhibits fast-responsive reversible photochromic properties. Moreover, it shows high efficiency and selective oxidation of 2,6-di-
-butylphenol to its quinone derivative, aldehyde, and dimeric or trimeric phenol derivative by controlling the reaction conditions.</description><subject>Aldehydes</subject><subject>Benzoic acid</subject><subject>Carbon</subject><subject>Diimide</subject><subject>Electrochromism</subject><subject>Electron transfer</subject><subject>Electrons</subject><subject>Energy transfer</subject><subject>Metal-organic frameworks</subject><subject>Naphthalene</subject><subject>Oxidation</subject><subject>Quadrupoles</subject><subject>Quinones</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkctOwzAQRS0EoqWw4QOQJTYIEbCd2ImXVUsBqaibso4cPyBVGhfbQfQv-GRMXwtWM5p75mo0F4BLjO4xSvmDIiogVDBujkAfZ3mecJJmx4eesB44836BECGIklPQSynNKSG0D36GLdSNlsHZNlHa1LLWbYCvswkUHooomv3sgAUnWm-0g1IE0ax9gMY66Dd6_aWh_a6V2HRSuCoubAuUtls1dfsOrYHkjiWqTmDQLsCk6sK6WX3o1jbn4MSIxuuLXR2At8njfPScTGdPL6PhNJGEs5CovDKc4RTlrJAiq0iKEGOMFoyS-AvKVGEQ59RolcUfUcorlqMsLZjGXIgiHYCbre_K2c9O-1Auay9104hW286XJJphTDjnEb3-hy5s59p4XaRyTDOaZzhSt1tKOuu906ZcuXop3LrEqPzLqRyT8XyT0yTCVzvLrlpqdUD3waS_buONAA</recordid><startdate>20220531</startdate><enddate>20220531</enddate><creator>Liu, Teng</creator><creator>Shen, Xianfu</creator><creator>Liu, Zhengfen</creator><creator>Zhang, Feng</creator><creator>Liu, Jian-Jun</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7480-0444</orcidid><orcidid>https://orcid.org/0000-0001-9912-5396</orcidid></search><sort><creationdate>20220531</creationdate><title>An electron-deficient MOF as an efficient electron-transfer catalyst for selective oxidative carbon-carbon coupling of 2,6-di- tert -butylphenol</title><author>Liu, Teng ; Shen, Xianfu ; Liu, Zhengfen ; Zhang, Feng ; Liu, Jian-Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-d7bf96130768ca4b23006665865200856d8f0995fed4039559b6704386e19aa83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aldehydes</topic><topic>Benzoic acid</topic><topic>Carbon</topic><topic>Diimide</topic><topic>Electrochromism</topic><topic>Electron transfer</topic><topic>Electrons</topic><topic>Energy transfer</topic><topic>Metal-organic frameworks</topic><topic>Naphthalene</topic><topic>Oxidation</topic><topic>Quadrupoles</topic><topic>Quinones</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Teng</creatorcontrib><creatorcontrib>Shen, Xianfu</creatorcontrib><creatorcontrib>Liu, Zhengfen</creatorcontrib><creatorcontrib>Zhang, Feng</creatorcontrib><creatorcontrib>Liu, Jian-Jun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Teng</au><au>Shen, Xianfu</au><au>Liu, Zhengfen</au><au>Zhang, Feng</au><au>Liu, Jian-Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An electron-deficient MOF as an efficient electron-transfer catalyst for selective oxidative carbon-carbon coupling of 2,6-di- tert -butylphenol</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2022-05-31</date><risdate>2022</risdate><volume>51</volume><issue>21</issue><spage>8234</spage><epage>8239</epage><pages>8234-8239</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Naphthalene diimides (NDIs), a type of electron-deficient dye molecule with high quadrupole moment and excellent redox activity, have been utilized in various fields, such as energy transfer, chemical sensing, anion transport, and photo-/electrochromic materials. In this study, an electron-deficient metal-organic framework with one-dimensional channels, Eu
(BBNDI)
(DMF)
(MOF 1) (H
BBNDI =
,
'-bis(3-benzoic acid)naphthalene diimide), was successfully constructed based on the naphthalene diimide derivative. Because of the generation of NDI radicals by electron transfer between components, this material exhibits fast-responsive reversible photochromic properties. Moreover, it shows high efficiency and selective oxidation of 2,6-di-
-butylphenol to its quinone derivative, aldehyde, and dimeric or trimeric phenol derivative by controlling the reaction conditions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35575225</pmid><doi>10.1039/d2dt00869f</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-7480-0444</orcidid><orcidid>https://orcid.org/0000-0001-9912-5396</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-05, Vol.51 (21), p.8234-8239 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2665112999 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Aldehydes Benzoic acid Carbon Diimide Electrochromism Electron transfer Electrons Energy transfer Metal-organic frameworks Naphthalene Oxidation Quadrupoles Quinones |
| title | An electron-deficient MOF as an efficient electron-transfer catalyst for selective oxidative carbon-carbon coupling of 2,6-di- tert -butylphenol |
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