Loading…
Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile)
Transport properties of copper salts were studied in a solvent-free polymer electrolyte PEO–Cu(CF 3SO 3) 2 (where PEO is poly(ethylene oxide)) as well as in gel-type polymer electrolytes: polymer–solvent–CuX 2 (where X=Cl −, Br − or CF 3SO 3 −, polymer is PEO or poly(acrylonitrile) (PAN), solvent is...
Saved in:
| Published in: | Solid state ionics 2001-07, Vol.143 (3), p.425-432 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c367t-43a2f6cedb0e4c0c1c4c7e6f1db668a517bd01286cff4eb4f031129c86e7ec63 |
|---|---|
| cites | |
| container_end_page | 432 |
| container_issue | 3 |
| container_start_page | 425 |
| container_title | Solid state ionics |
| container_volume | 143 |
| creator | Lewandowski, Andrzej Stȩpniak, Izabela Grzybkowski, Wacław |
| description | Transport properties of copper salts were studied in a solvent-free polymer electrolyte PEO–Cu(CF
3SO
3)
2 (where PEO is poly(ethylene oxide)) as well as in gel-type polymer electrolytes: polymer–solvent–CuX
2 (where X=Cl
−, Br
− or CF
3SO
3
−, polymer is PEO or poly(acrylonitrile) (PAN), solvent is dimethylsulfoxide (DMSO), sulfolane or propylene carbonate). Generally, low values of the cationic transference numbers (
T
+≈0.02–0.08) for the polymer electrolytes were obtained. However, in the systems based on PAN plasticised with DMSO, the
T
+ value increases significantly (
T
+≈0.1–0.4); the highest value is reached in the system containing an excess of the Br
− anions (PAN–DMSO–CuX
2–KBr,
T
+=0.4). |
| doi_str_mv | 10.1016/S0167-2738(01)00868-2 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_26669085</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0167273801008682</els_id><sourcerecordid>26669085</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-43a2f6cedb0e4c0c1c4c7e6f1db668a517bd01286cff4eb4f031129c86e7ec63</originalsourceid><addsrcrecordid>eNqFkE9LAzEQxYMoWKsfQdiDSHtYTbLbbPYkUvwHBQ_2HrLZCUbSzZqk4n57024Rb14SMu_NTN4PoUuCbwgm7PYtHVVOq4LPMJljzBnP6RGaEF7RvGK8PkaTX8spOgvhA2PMCs4myCxd34PPopdd6J2PWe9dKkQDITNd1js7bJIOFlT06RFTvZEB2syN6gzi-2Chg8x9mxbmmezaUZDKD9Z1JnpjYX6OTrS0AS4O9xStHx_Wy-d89fr0srxf5apgVczLQlLNFLQNhlJhRVSpKmCatA1jXC5I1bSYUM6U1iU0pcYFIbRWnEEFihVTdD2OTTk-txCi2JigwFrZgdsGQRljNeaLZFyMRuVdCB606L3ZSD8IgsWOq9hzFTtoAhOx5ypo6rs6LJBBSasTOGXCn-aaFvXuH3ejDVLWLwNeBGWgS8GMTyhF68w_i34AhAuPVA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>26669085</pqid></control><display><type>article</type><title>Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile)</title><source>ScienceDirect Journals</source><creator>Lewandowski, Andrzej ; Stȩpniak, Izabela ; Grzybkowski, Wacław</creator><creatorcontrib>Lewandowski, Andrzej ; Stȩpniak, Izabela ; Grzybkowski, Wacław</creatorcontrib><description>Transport properties of copper salts were studied in a solvent-free polymer electrolyte PEO–Cu(CF
3SO
3)
2 (where PEO is poly(ethylene oxide)) as well as in gel-type polymer electrolytes: polymer–solvent–CuX
2 (where X=Cl
−, Br
− or CF
3SO
3
−, polymer is PEO or poly(acrylonitrile) (PAN), solvent is dimethylsulfoxide (DMSO), sulfolane or propylene carbonate). Generally, low values of the cationic transference numbers (
T
+≈0.02–0.08) for the polymer electrolytes were obtained. However, in the systems based on PAN plasticised with DMSO, the
T
+ value increases significantly (
T
+≈0.1–0.4); the highest value is reached in the system containing an excess of the Br
− anions (PAN–DMSO–CuX
2–KBr,
T
+=0.4).</description><identifier>ISSN: 0167-2738</identifier><identifier>EISSN: 1872-7689</identifier><identifier>DOI: 10.1016/S0167-2738(01)00868-2</identifier><identifier>CODEN: SSIOD3</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Copper ; Electrical, magnetic and optical properties ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymer electrolyte ; Properties and characterization ; Transference number</subject><ispartof>Solid state ionics, 2001-07, Vol.143 (3), p.425-432</ispartof><rights>2001 Elsevier Science B.V.</rights><rights>2001 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-43a2f6cedb0e4c0c1c4c7e6f1db668a517bd01286cff4eb4f031129c86e7ec63</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1092396$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lewandowski, Andrzej</creatorcontrib><creatorcontrib>Stȩpniak, Izabela</creatorcontrib><creatorcontrib>Grzybkowski, Wacław</creatorcontrib><title>Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile)</title><title>Solid state ionics</title><description>Transport properties of copper salts were studied in a solvent-free polymer electrolyte PEO–Cu(CF
3SO
3)
2 (where PEO is poly(ethylene oxide)) as well as in gel-type polymer electrolytes: polymer–solvent–CuX
2 (where X=Cl
−, Br
− or CF
3SO
3
−, polymer is PEO or poly(acrylonitrile) (PAN), solvent is dimethylsulfoxide (DMSO), sulfolane or propylene carbonate). Generally, low values of the cationic transference numbers (
T
+≈0.02–0.08) for the polymer electrolytes were obtained. However, in the systems based on PAN plasticised with DMSO, the
T
+ value increases significantly (
T
+≈0.1–0.4); the highest value is reached in the system containing an excess of the Br
− anions (PAN–DMSO–CuX
2–KBr,
T
+=0.4).</description><subject>Applied sciences</subject><subject>Copper</subject><subject>Electrical, magnetic and optical properties</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer electrolyte</subject><subject>Properties and characterization</subject><subject>Transference number</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LAzEQxYMoWKsfQdiDSHtYTbLbbPYkUvwHBQ_2HrLZCUbSzZqk4n57024Rb14SMu_NTN4PoUuCbwgm7PYtHVVOq4LPMJljzBnP6RGaEF7RvGK8PkaTX8spOgvhA2PMCs4myCxd34PPopdd6J2PWe9dKkQDITNd1js7bJIOFlT06RFTvZEB2syN6gzi-2Chg8x9mxbmmezaUZDKD9Z1JnpjYX6OTrS0AS4O9xStHx_Wy-d89fr0srxf5apgVczLQlLNFLQNhlJhRVSpKmCatA1jXC5I1bSYUM6U1iU0pcYFIbRWnEEFihVTdD2OTTk-txCi2JigwFrZgdsGQRljNeaLZFyMRuVdCB606L3ZSD8IgsWOq9hzFTtoAhOx5ypo6rs6LJBBSasTOGXCn-aaFvXuH3ejDVLWLwNeBGWgS8GMTyhF68w_i34AhAuPVA</recordid><startdate>20010702</startdate><enddate>20010702</enddate><creator>Lewandowski, Andrzej</creator><creator>Stȩpniak, Izabela</creator><creator>Grzybkowski, Wacław</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20010702</creationdate><title>Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile)</title><author>Lewandowski, Andrzej ; Stȩpniak, Izabela ; Grzybkowski, Wacław</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-43a2f6cedb0e4c0c1c4c7e6f1db668a517bd01286cff4eb4f031129c86e7ec63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Applied sciences</topic><topic>Copper</topic><topic>Electrical, magnetic and optical properties</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer electrolyte</topic><topic>Properties and characterization</topic><topic>Transference number</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lewandowski, Andrzej</creatorcontrib><creatorcontrib>Stȩpniak, Izabela</creatorcontrib><creatorcontrib>Grzybkowski, Wacław</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lewandowski, Andrzej</au><au>Stȩpniak, Izabela</au><au>Grzybkowski, Wacław</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile)</atitle><jtitle>Solid state ionics</jtitle><date>2001-07-02</date><risdate>2001</risdate><volume>143</volume><issue>3</issue><spage>425</spage><epage>432</epage><pages>425-432</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><coden>SSIOD3</coden><abstract>Transport properties of copper salts were studied in a solvent-free polymer electrolyte PEO–Cu(CF
3SO
3)
2 (where PEO is poly(ethylene oxide)) as well as in gel-type polymer electrolytes: polymer–solvent–CuX
2 (where X=Cl
−, Br
− or CF
3SO
3
−, polymer is PEO or poly(acrylonitrile) (PAN), solvent is dimethylsulfoxide (DMSO), sulfolane or propylene carbonate). Generally, low values of the cationic transference numbers (
T
+≈0.02–0.08) for the polymer electrolytes were obtained. However, in the systems based on PAN plasticised with DMSO, the
T
+ value increases significantly (
T
+≈0.1–0.4); the highest value is reached in the system containing an excess of the Br
− anions (PAN–DMSO–CuX
2–KBr,
T
+=0.4).</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/S0167-2738(01)00868-2</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0167-2738 |
| ispartof | Solid state ionics, 2001-07, Vol.143 (3), p.425-432 |
| issn | 0167-2738 1872-7689 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26669085 |
| source | ScienceDirect Journals |
| subjects | Applied sciences Copper Electrical, magnetic and optical properties Exact sciences and technology Organic polymers Physicochemistry of polymers Polymer electrolyte Properties and characterization Transference number |
| title | Copper transport properties in polymer electrolytes based on poly(ethylene oxide) and poly(acrylonitrile) |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-30T21%3A53%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Copper%20transport%20properties%20in%20polymer%20electrolytes%20based%20on%20poly(ethylene%20oxide)%20and%20poly(acrylonitrile)&rft.jtitle=Solid%20state%20ionics&rft.au=Lewandowski,%20Andrzej&rft.date=2001-07-02&rft.volume=143&rft.issue=3&rft.spage=425&rft.epage=432&rft.pages=425-432&rft.issn=0167-2738&rft.eissn=1872-7689&rft.coden=SSIOD3&rft_id=info:doi/10.1016/S0167-2738(01)00868-2&rft_dat=%3Cproquest_cross%3E26669085%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c367t-43a2f6cedb0e4c0c1c4c7e6f1db668a517bd01286cff4eb4f031129c86e7ec63%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=26669085&rft_id=info:pmid/&rfr_iscdi=true |