Chemical and Electrochemical Manipulation of Mechanical Properties in Stimuli-Responsive Copper-Cross-Linked Hydrogels

Inspiration for the design of new synthetic polymers can be found in the natural world, where materials often exhibit complex properties that change depending on external stimuli. A new synthetic electroplastic elastomer hydrogel (EPEH) that undergoes changes in mechanical properties in response to...

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Bibliographic Details
Published in:ACS macro letters 2013-12, Vol.2 (12), p.1095-1099
Main Authors: Harris, Rachel D, Auletta, Jeffrey T, Motlagh, S. Amin Mohaghegh, Lawless, Matthew J, Perri, Nicholas M, Saxena, Sunil, Weiland, Lisa M, Waldeck, David H, Clark, William W, Meyer, Tara Y
Format: Article
Language:English
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Summary:Inspiration for the design of new synthetic polymers can be found in the natural world, where materials often exhibit complex properties that change depending on external stimuli. A new synthetic electroplastic elastomer hydrogel (EPEH) that undergoes changes in mechanical properties in response to both chemical and electrochemical stimuli has been prepared based on these precedents. In addition to having the capability to switch between hard and soft states, the presence of both permanent covalent and dynamic copper-based cross links also allows this stimuli-responsive material to exhibit a striking shape memory capability. The density of temporary cross links and the mechanical properties are controlled by reversible switching between the +1 and +2 oxidation states.
ISSN:2161-1653
2161-1653
DOI:10.1021/mz4004997