Living supramolecular polymerization of an amphiphilic aza-BODIPY dye realized by water-assisted kinetic trapping

The kinetic assembly pathways of a newly synthesized amphiphilic aza-BODIPY dye 1 were tuned by using H 2 O as a co-solvent in MeOH. Accordingly, the biphasic aggregation pathways resulting in kinetically-trapped and thermodynamically stable aggregates of 1 were established and the multiple cyclic s...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-07, Vol.58 (55), p.7662-7665
Main Authors: Liu, Yan, Pan, Hongfei, Yuan, Siyuan, Ding, Jiahui, Jiang, Yuanyuan, Ren, Xiang-Kui, Chen, Zhijian
Format: Article
Language:English
Subjects:
Dyes
Polymerization
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Summary:The kinetic assembly pathways of a newly synthesized amphiphilic aza-BODIPY dye 1 were tuned by using H 2 O as a co-solvent in MeOH. Accordingly, the biphasic aggregation pathways resulting in kinetically-trapped and thermodynamically stable aggregates of 1 were established and the multiple cyclic seeded living supramolecular polymerization of this dye was realized. A kinetic-controlled aggregation pathway of amphiphilic aza-BODIPY 1 was established by using H 2 O as a co-solvent in MeOH and living supramolecular polymerization was realized for this dye.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc02437c