Effect of silicones and polymers on the wetting and foaming properties of anionic and nonionic hydrocarbon surfactants

• Published in: Environmental science and pollution research international 2022-11, Vol.29 (54), p.81713-81725
• Main Authors: Wang, Qingguo, Tuo, Lina, Zhou, Gang, Zhang, Yuanyuan, Geng, Xu, Zhang, Fasong, Li, Yonghe
• Format: Article
• Language: English
• Subjects: Addition polymerization; Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Defoaming; Earth and Environmental Science; Ecotoxicology; Electronegativity; Environment; Environmental Chemistry; Environmental Health; Environmental science; Foaming; Half-life; Hydrocarbons; Nonionic surfactants; Polymers; Research Article; Silicone resins; Silicones; Siloxanes; Stability; Surface tension; Surfactants; Waste Water Technology; Water Management; Water Pollution Control; Wetting
• ISSN: 0944-1344; 1614-7499
• DOI: 10.1007/s11356-022-21517-y

To better understand the effects of nonionic silicones and polymers on the wetting and foaming properties of anionic and nonionic hydrocarbon surfactants and different forces between molecules, nonionic silicone surfactant (GT-248), polymer (HPMC), anionic surfactant (AES), and nonionic surfactants (APG0810) were selected. The CMC ratio is used as a reference to determine the concentration ratio of the APG0810/GT-248 and AES/GT-248 compound solutions, after which HPMC was added to form a compound solution to test the wetting and foaming properties of the compound solution. The results showed that GT-248 obtained a high density of methyl groups on the surface of the solution due to its excellent spreadability and good flexibility of the siloxane chain, effectively reduces the surface tension and wetting time of AES and APG0810 solutions. But in terms of foam performance, after adding GT-248 to solution, the foam stability of AES solution is enhanced, the foam height of AES solution was reduced by 33.7%, the foam stability of APG0810 solution is weakened a lot, and the foam height of APG0810 solution was reduced by 85.4%. Mainly because of the difference in electronegativity between the AES and APG0810 head groups, the strong electronegativity between the AES head groups resulted in a smaller number of GT-248 insertions in the liquid film, which weakened the defoaming effect of GT-248. The weak interaction between the head groups of APG0810 resulted in a higher amount of GT-248 in the liquid film, and thus, the foam performance was greatly reduced. After the AES/GT-248 compound solution was preferred, by comparing the viscosity, surface tension, and the half-life of the foam, it was found that the addition of low concentration of polymer effectively improved the half-life of the foam without affecting the foaming properties, and the final choice of 4:1(AES/GT-248) + 1mgHPMC and 2:1(AES/GT-248) + 1mgHPMC composite solutions can be used as a superior dust suppression material.