Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)

A comparative study has been made of the crosslinking of plasticized PVC by grafting of γ‐aminopropyltriethoxysilane (ASi) and sodium γ‐mercaptopropyltrimethoxysilane (NaMSi) during processing. The influence of type of reagent and concentration, and the rheological behavior were investigated to obta...

Full description

Saved in:
Bibliographic Details
Published in:Journal of applied polymer science 1998-10, Vol.70 (5), p.865-872
Main Authors: Hidalgo, M., Beltrán, M. I., Reinecke, H., Mijangos, C.
Format: Article
Language:English
Subjects:
Applied sciences
Chemical reactions and properties
crosslinked poly(vinylchloride)
Crosslinking, vulcanization
Exact sciences and technology
gel content
mechanical and thermal properties
Organic polymers
organosilanes grafting
Physicochemistry of polymers
reactive processing
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 872
container_issue 5
container_start_page 865
container_title Journal of applied polymer science
container_volume 70
creator Hidalgo, M.
Beltrán, M. I.
Reinecke, H.
Mijangos, C.
description A comparative study has been made of the crosslinking of plasticized PVC by grafting of γ‐aminopropyltriethoxysilane (ASi) and sodium γ‐mercaptopropyltrimethoxysilane (NaMSi) during processing. The influence of type of reagent and concentration, and the rheological behavior were investigated to obtain a crosslinked material with improved mechanical properties and good thermal stability. Depending on the reagent concentration, different gel contents, ranging from 0–100%, were obtained with both reagents. For all crosslinked systems the mechanical properties above Tg were improved. In the case of ASi‐crosslinked PVC, the thermal stability deteriorated significantly but, for NaMSi‐crosslinked PVC, thermal stability remains close to that of raw PVC, and the separation of the grafting and crosslinking processes is more viable in this case. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 70: 865–872, 1998
doi_str_mv 10.1002/(SICI)1097-4628(19981031)70:5<865::AID-APP5>3.0.CO;2-R
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_26815843</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>26815843</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4465-c5f64f50e9cdbed4c8a919754c372339588b9917a18c912245c7826c34452d073</originalsourceid><addsrcrecordid>eNqFkM1uEzEUhS0EEqHwDrNAKFlM8P9PQJWiAUpERUopZXnlejyK6WQmtVMgb4-nKWEBEgvLutL1d44_hI4JnhKM6cvx50W1mBBsVMkl1WNijCaYkYnCM_FaSzGbzRdvyvnZmThmUzytlq9oef4AjQ5PHqJRBpFSGyMeoycpfcOYEIHlCH24WPm4tm1hu7pYe7eyXXB53MR-4-M2-FT0TZFCaztfutin1Ibu2tfFpm934--h27Vu1fYx1H7yFD1qbJv8s_v7CH159_aiel-eLk8W1fy0dJxLUTrRSN4I7I2rr3zNnbaGGCW4Y4oyZoTWV8YQZYl2hlDKhVOaSsc4F7TGih2hF3tuLnlz69MW1iE53w4d-9sEVGoiNGd58XK_eFc8-gY2Maxt3AHBMLgFGNzCIAoGUfDbLSgMArJbgOwWBrfAAEO1BArnGfz8voFN2VYTbedCOtBp_giV-E_-j9D63V_h_83-R_TdnMHlHhzS1v88gG28BqmYEvD140k-SulP8hI0-wU3F6ed</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>26815843</pqid></control><display><type>article</type><title>Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)</title><source>Wiley</source><creator>Hidalgo, M. ; Beltrán, M. I. ; Reinecke, H. ; Mijangos, C.</creator><creatorcontrib>Hidalgo, M. ; Beltrán, M. I. ; Reinecke, H. ; Mijangos, C.</creatorcontrib><description>A comparative study has been made of the crosslinking of plasticized PVC by grafting of γ‐aminopropyltriethoxysilane (ASi) and sodium γ‐mercaptopropyltrimethoxysilane (NaMSi) during processing. The influence of type of reagent and concentration, and the rheological behavior were investigated to obtain a crosslinked material with improved mechanical properties and good thermal stability. Depending on the reagent concentration, different gel contents, ranging from 0–100%, were obtained with both reagents. For all crosslinked systems the mechanical properties above Tg were improved. In the case of ASi‐crosslinked PVC, the thermal stability deteriorated significantly but, for NaMSi‐crosslinked PVC, thermal stability remains close to that of raw PVC, and the separation of the grafting and crosslinking processes is more viable in this case. © 1998 John Wiley &amp; Sons, Inc. J. Appl. Polym. Sci. 70: 865–872, 1998</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/(SICI)1097-4628(19981031)70:5&lt;865::AID-APP5&gt;3.0.CO;2-R</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: John Wiley &amp; Sons, Inc</publisher><subject>Applied sciences ; Chemical reactions and properties ; crosslinked poly(vinylchloride) ; Crosslinking, vulcanization ; Exact sciences and technology ; gel content ; mechanical and thermal properties ; Organic polymers ; organosilanes grafting ; Physicochemistry of polymers ; reactive processing</subject><ispartof>Journal of applied polymer science, 1998-10, Vol.70 (5), p.865-872</ispartof><rights>Copyright © 1998 John Wiley &amp; Sons, Inc.</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=2372260$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hidalgo, M.</creatorcontrib><creatorcontrib>Beltrán, M. I.</creatorcontrib><creatorcontrib>Reinecke, H.</creatorcontrib><creatorcontrib>Mijangos, C.</creatorcontrib><title>Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A comparative study has been made of the crosslinking of plasticized PVC by grafting of γ‐aminopropyltriethoxysilane (ASi) and sodium γ‐mercaptopropyltrimethoxysilane (NaMSi) during processing. The influence of type of reagent and concentration, and the rheological behavior were investigated to obtain a crosslinked material with improved mechanical properties and good thermal stability. Depending on the reagent concentration, different gel contents, ranging from 0–100%, were obtained with both reagents. For all crosslinked systems the mechanical properties above Tg were improved. In the case of ASi‐crosslinked PVC, the thermal stability deteriorated significantly but, for NaMSi‐crosslinked PVC, thermal stability remains close to that of raw PVC, and the separation of the grafting and crosslinking processes is more viable in this case. © 1998 John Wiley &amp; Sons, Inc. J. Appl. Polym. Sci. 70: 865–872, 1998</description><subject>Applied sciences</subject><subject>Chemical reactions and properties</subject><subject>crosslinked poly(vinylchloride)</subject><subject>Crosslinking, vulcanization</subject><subject>Exact sciences and technology</subject><subject>gel content</subject><subject>mechanical and thermal properties</subject><subject>Organic polymers</subject><subject>organosilanes grafting</subject><subject>Physicochemistry of polymers</subject><subject>reactive processing</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkM1uEzEUhS0EEqHwDrNAKFlM8P9PQJWiAUpERUopZXnlejyK6WQmtVMgb4-nKWEBEgvLutL1d44_hI4JnhKM6cvx50W1mBBsVMkl1WNijCaYkYnCM_FaSzGbzRdvyvnZmThmUzytlq9oef4AjQ5PHqJRBpFSGyMeoycpfcOYEIHlCH24WPm4tm1hu7pYe7eyXXB53MR-4-M2-FT0TZFCaztfutin1Ibu2tfFpm934--h27Vu1fYx1H7yFD1qbJv8s_v7CH159_aiel-eLk8W1fy0dJxLUTrRSN4I7I2rr3zNnbaGGCW4Y4oyZoTWV8YQZYl2hlDKhVOaSsc4F7TGih2hF3tuLnlz69MW1iE53w4d-9sEVGoiNGd58XK_eFc8-gY2Maxt3AHBMLgFGNzCIAoGUfDbLSgMArJbgOwWBrfAAEO1BArnGfz8voFN2VYTbedCOtBp_giV-E_-j9D63V_h_83-R_TdnMHlHhzS1v88gG28BqmYEvD140k-SulP8hI0-wU3F6ed</recordid><startdate>19981031</startdate><enddate>19981031</enddate><creator>Hidalgo, M.</creator><creator>Beltrán, M. I.</creator><creator>Reinecke, H.</creator><creator>Mijangos, C.</creator><general>John Wiley &amp; Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19981031</creationdate><title>Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)</title><author>Hidalgo, M. ; Beltrán, M. I. ; Reinecke, H. ; Mijangos, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4465-c5f64f50e9cdbed4c8a919754c372339588b9917a18c912245c7826c34452d073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Chemical reactions and properties</topic><topic>crosslinked poly(vinylchloride)</topic><topic>Crosslinking, vulcanization</topic><topic>Exact sciences and technology</topic><topic>gel content</topic><topic>mechanical and thermal properties</topic><topic>Organic polymers</topic><topic>organosilanes grafting</topic><topic>Physicochemistry of polymers</topic><topic>reactive processing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hidalgo, M.</creatorcontrib><creatorcontrib>Beltrán, M. I.</creatorcontrib><creatorcontrib>Reinecke, H.</creatorcontrib><creatorcontrib>Mijangos, C.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hidalgo, M.</au><au>Beltrán, M. I.</au><au>Reinecke, H.</au><au>Mijangos, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1998-10-31</date><risdate>1998</risdate><volume>70</volume><issue>5</issue><spage>865</spage><epage>872</epage><pages>865-872</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A comparative study has been made of the crosslinking of plasticized PVC by grafting of γ‐aminopropyltriethoxysilane (ASi) and sodium γ‐mercaptopropyltrimethoxysilane (NaMSi) during processing. The influence of type of reagent and concentration, and the rheological behavior were investigated to obtain a crosslinked material with improved mechanical properties and good thermal stability. Depending on the reagent concentration, different gel contents, ranging from 0–100%, were obtained with both reagents. For all crosslinked systems the mechanical properties above Tg were improved. In the case of ASi‐crosslinked PVC, the thermal stability deteriorated significantly but, for NaMSi‐crosslinked PVC, thermal stability remains close to that of raw PVC, and the separation of the grafting and crosslinking processes is more viable in this case. © 1998 John Wiley &amp; Sons, Inc. J. Appl. Polym. Sci. 70: 865–872, 1998</abstract><cop>New York</cop><pub>John Wiley &amp; Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19981031)70:5&lt;865::AID-APP5&gt;3.0.CO;2-R</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-8995
ispartof Journal of applied polymer science, 1998-10, Vol.70 (5), p.865-872
issn 0021-8995
1097-4628
language eng
recordid cdi_proquest_miscellaneous_26815843
source Wiley
subjects Applied sciences
Chemical reactions and properties
crosslinked poly(vinylchloride)
Crosslinking, vulcanization
Exact sciences and technology
gel content
mechanical and thermal properties
Organic polymers
organosilanes grafting
Physicochemistry of polymers
reactive processing
title Thermal and mechanical properties of silane-crosslinked poly(vinylchloride)
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T23%3A45%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermal%20and%20mechanical%20properties%20of%20silane-crosslinked%20poly(vinylchloride)&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Hidalgo,%20M.&rft.date=1998-10-31&rft.volume=70&rft.issue=5&rft.spage=865&rft.epage=872&rft.pages=865-872&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/(SICI)1097-4628(19981031)70:5%3C865::AID-APP5%3E3.0.CO;2-R&rft_dat=%3Cproquest_cross%3E26815843%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4465-c5f64f50e9cdbed4c8a919754c372339588b9917a18c912245c7826c34452d073%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=26815843&rft_id=info:pmid/&rfr_iscdi=true