Silica-coated modified magnetic nanoparticles (Fe3O4@SiO2@(BuSO3H)3) as an efficient adsorbent for Pd2+ removal

• Published in: Chemosphere (Oxford) 2022-11, Vol.307 (Pt 1), p.135622
• Main Authors: Jamasbi, Negar, Mohammadi Ziarani, Ghodsi, Mohajer, Fatemeh, Darroudi, Mahdieh, Badiei, Alireza, Varma, Rajender S, Karimi, Fatemeh
• Format: Article
• Language: English
• ISSN: 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2022.135622

It is crucial to fabricate cost-effective and efficient strategies for monitoring and eliminating hazardous metals in the water supplies. Among the many techniques, adsorption is one of the most powerful and facile ways for eliminating pollutants from effluents. It is also crucial to engineering high-performance low-cost adsorbents. In this regard, herein, Fe3O4@SiO2@(BuSO3H)3 as a modified core-shell magnetic silica nanoparticle embodies good selectivity to extract toxic metal ions from aquatic media. The present work investigated the removal performance of the magnetic adsorbent towards Pd2+ cation amongst the other heavy metal ions including Co2+, Pb2+, Hg2+, Cd2+, Cu2+, Zn2+ in aqueous solution. The flame atomic absorption spectrometry (FAAS) was utilized to assess the removal efficiency of the adsorbent. Several experimental parameters including elution condition, initial Pd(II) concentration, adsorbent dosage, initial pH of the solution, and contact time were explored to achieve the optimal conditions. The data of adsorption were very well with the Langmuir isotherm model, according to the adsorption isotherm mechanism experiments. In conclusion, this study lays the way for the development of novel magnetic adsorbents with high removal efficiencies for the removal of toxic metal ions from aqueous environment.It is crucial to fabricate cost-effective and efficient strategies for monitoring and eliminating hazardous metals in the water supplies. Among the many techniques, adsorption is one of the most powerful and facile ways for eliminating pollutants from effluents. It is also crucial to engineering high-performance low-cost adsorbents. In this regard, herein, Fe3O4@SiO2@(BuSO3H)3 as a modified core-shell magnetic silica nanoparticle embodies good selectivity to extract toxic metal ions from aquatic media. The present work investigated the removal performance of the magnetic adsorbent towards Pd2+ cation amongst the other heavy metal ions including Co2+, Pb2+, Hg2+, Cd2+, Cu2+, Zn2+ in aqueous solution. The flame atomic absorption spectrometry (FAAS) was utilized to assess the removal efficiency of the adsorbent. Several experimental parameters including elution condition, initial Pd(II) concentration, adsorbent dosage, initial pH of the solution, and contact time were explored to achieve the optimal conditions. The data of adsorption were very well with the Langmuir isotherm model, according to the adsorption isotherm mechanism experiments. In concl