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Properties of sol-gel derived strontium barium niobate ceramics and the effect of V2O5 additive

Strontium barium niobate, SrxBa1−xNb2O6, (SBN) ceramics with a range of Sr/Ba ratios were fabricated using a solution chemistry approach with alkoxides dissolved in acetic acid. Powders obtained from dried gels were calcined at 800°C for three hours, a heat treatment that produced fully crystalline...

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Published in:Journal of materials science 2001-11, Vol.36 (22), p.5519-5527
Main Authors: ORAL, A. Y, MECARTNEY, M. L
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description Strontium barium niobate, SrxBa1−xNb2O6, (SBN) ceramics with a range of Sr/Ba ratios were fabricated using a solution chemistry approach with alkoxides dissolved in acetic acid. Powders obtained from dried gels were calcined at 800°C for three hours, a heat treatment that produced fully crystalline powders. After preparing bulk ceramics from these powders by sintering at 1200°C for 1–24 hours, the tetragonal tungsten bronze (TTB) phase was present in all compositions between 0 ≤ x≤ 1, although not predicted by the phase diagram for BaNb2O6and SrNb2O6. Vanadium pentoxide (V2O5) additions increased the densification, the amount of tungsten bronze phase, and the dielectric constant for all compositions except for Sr0.65Ba0.35Nb2O6(SBN65) ceramics.
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source Springer Nature
subjects Acetic acid
Alkoxides
Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Ceramic powders
Ceramics
Chemical industry and chemicals
Composition
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Densification
Dielectric properties of solids and liquids
Dielectric, piezoelectric, ferroelectric and antiferroelectric materials
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Electrotechnical and electronic ceramics
Exact sciences and technology
Gels
Heat treatment
Materials science
Niobates, titanates, tantalates, pzt ceramics, etc
Organic chemistry
Permittivity (dielectric function)
Phase diagrams
Physics
Sintering (powder metallurgy)
Sol-gel processes
Strontium
Strontium barium niobate
Technical ceramics
Tungsten bronze
Vanadium pentoxide
title Properties of sol-gel derived strontium barium niobate ceramics and the effect of V2O5 additive
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