Fabrication, characterization, and photocatalytic degradation potential of chitosan-conjugated manganese magnetic nano-biocomposite for emerging dye pollutants

• Published in: Chemosphere (Oxford) 2022-11, Vol.306, p.135647-135647, Article 135647
• Main Authors: Yang, Yong, Khan, Hamayun, Gao, Shixiong, Khalil, Abdul Kabir, Ali, Nisar, Khan, Adnan, Show, Pau Loke, Bilal, Muhammad, Khan, Hammad
• Format: Article
• Language: English
• Subjects: Chitosan; Crystal violet; Environmental pollution; Magnetic nano-biocomposite; Photocatalysis; Reusability
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2022.135647

The release of toxic dyes from different industries through industrial effluents cause hazardous effects to human and aquatic life. Therefore, the detoxification of such toxic pollutants is very important for a clean environment. In this regard, chitosan conjugated Mn-magnetic nano-biocomposite (Mn-CCMN) was synthesized, characterized, and applied for the photocatalytic decontamination of crystal violet (CV) dye in the contaminated aqueous system and industrial wastewater. The characterization was performed using SEM, XRD, EDX and FTIR spectroscopic techniques and determine PZC. The data shows the successfully synthesis of the resultant nano-biocomposite with amorphous nature and Fe and Mn were present therein. The SEM study revealed the flat and irregular shaped structure with porous surface and 87 ± 4 nm as mean particle size. The application of as-synthesized nano-biocomposite was determined as a photocatalyst for the eradication of CV in the aqueous environment under UV light illumination. The different photocatalysis conditions were studied for maximum degradation of CV and under the best experimental factors, tremendous CV degradation was attained in the real samples and industrial wastewater. The synthesized Mn-CCMN sustain excellent photocatalytic performance for four successive batches. The photocatalytic data was fitted to the pseudo-first-order kinetic model (R2 = 0.992) having 0.007672 min−1 and 0.0549 ppm/min as k and reaction rate, respectively. The statistical models such as response surface methodology (RSM) and artificial neural network-genetic algorithm (ANN-GA) were also applied for confirmation of the experimental data and the results showed a good agreement. It is deduced that the synthesized Mn-CCMN could be an excellent alternative to the present photocatalysts for the decontamination of toxic organic dyes from contaminated water and industrial wastewater. [Display omitted] •Design and development of chitosan-conjugated manganese magnetic nano-biocomposite.•The successful synthesis and characterization of nano-biocomposite using an arrary of advanced analytical techniques.•Highly efficient photocatalytic degradation of carcinogenic crystal violet dye under UV light irradiation.•Operating factors influencing the degradation phenomena were investigated experimentally and via RSM and ANN-GA.