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Excimer laser deposition and characteristics of tin oxide thin films

ArF excimer laser assisted chemical vapor deposition of tin oxide thin films on Si was obtained using SnCl 4 and O 2as precursors. Experimental measurements revealed that the deposition rate increases with incident laser energy density. The composition, structure and ultraviolet-to-visible spectra o...

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Published in:Thin solid films 1998-05, Vol.320 (2), p.216-219
Main Authors: Dai, Guorui, Jiang, Xilan, Zhang, Yushu
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Language:English
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cited_by cdi_FETCH-LOGICAL-c367t-18c591f2f6e412658464d89f090908b545ba967df28cc470eca8b09fea3de7023
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description ArF excimer laser assisted chemical vapor deposition of tin oxide thin films on Si was obtained using SnCl 4 and O 2as precursors. Experimental measurements revealed that the deposition rate increases with incident laser energy density. The composition, structure and ultraviolet-to-visible spectra of the thin films were investigated by means of XPS, SEM, XRD and a UV–Vis techniques. It was shown that SnO 2and SnOCl 2 coexisted in the thin films, and SnOCl 2 was almost completely converted into SnO 2 after annealing. The SnO 2 thin films deposited at room temperature were amorphous in structure and the grain size of the films became larger after annealing. The transmittance of the SnO 2 thin films is above 90%, the absorption edge is 355 nm and the energy gap is 3.49 eV.
doi_str_mv 10.1016/S0040-6090(97)01006-7
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subjects Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Excimer laser
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Tin oxide thin films
Vapor deposition
title Excimer laser deposition and characteristics of tin oxide thin films
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