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Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte
Composite electrolytes of the lithium-ion-conducting ceramic Li 1.3Al 0.3Ti 1.7(PO 4) 3 and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, t...
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| Published in: | Solid state ionics 1999, Vol.121 (1), p.115-119 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c367t-23ca620a13599a026bfa024a03228a603d6c0bd1282f2336e47fec5aefbd2b683 |
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| container_end_page | 119 |
| container_issue | 1 |
| container_start_page | 115 |
| container_title | Solid state ionics |
| container_volume | 121 |
| creator | Nairn, K.M Best, A.S Newman, P.J MacFarlane, D.R Forsyth, M |
| description | Composite electrolytes of the lithium-ion-conducting ceramic Li
1.3Al
0.3Ti
1.7(PO
4)
3 and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, the composites are no more conductive than the pure polymer electrolyte. Exposing the samples to the vapour of solvents such as DMF, acetonitrile or water produces a significant increase in conductivity, over and beyond simple plasticization of the polymer. Pretreating the ceramic with a compatibilizing agent improves adhesion at the interface with the polymer, but decreases overall conductivity in the case investigated. |
| doi_str_mv | 10.1016/S0167-2738(98)00537-2 |
| format | article |
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1.3Al
0.3Ti
1.7(PO
4)
3 and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, the composites are no more conductive than the pure polymer electrolyte. Exposing the samples to the vapour of solvents such as DMF, acetonitrile or water produces a significant increase in conductivity, over and beyond simple plasticization of the polymer. Pretreating the ceramic with a compatibilizing agent improves adhesion at the interface with the polymer, but decreases overall conductivity in the case investigated.</description><identifier>ISSN: 0167-2738</identifier><identifier>EISSN: 1872-7689</identifier><identifier>DOI: 10.1016/S0167-2738(98)00537-2</identifier><identifier>CODEN: SSIOD3</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Chemistry ; Electrochemistry ; Exact sciences and technology ; General and physical chemistry ; Properties of electrolytes: conductivity</subject><ispartof>Solid state ionics, 1999, Vol.121 (1), p.115-119</ispartof><rights>1999 Elsevier Science B.V.</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-23ca620a13599a026bfa024a03228a603d6c0bd1282f2336e47fec5aefbd2b683</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,4024,4050,4051,23930,23931,25140,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1796495$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nairn, K.M</creatorcontrib><creatorcontrib>Best, A.S</creatorcontrib><creatorcontrib>Newman, P.J</creatorcontrib><creatorcontrib>MacFarlane, D.R</creatorcontrib><creatorcontrib>Forsyth, M</creatorcontrib><title>Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte</title><title>Solid state ionics</title><description>Composite electrolytes of the lithium-ion-conducting ceramic Li
1.3Al
0.3Ti
1.7(PO
4)
3 and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, the composites are no more conductive than the pure polymer electrolyte. Exposing the samples to the vapour of solvents such as DMF, acetonitrile or water produces a significant increase in conductivity, over and beyond simple plasticization of the polymer. Pretreating the ceramic with a compatibilizing agent improves adhesion at the interface with the polymer, but decreases overall conductivity in the case investigated.</description><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Properties of electrolytes: conductivity</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFUMtKxDAUDaLgOPoJQhciuqimyTRNVyKDLxBcqOtwJ71hIm1Tk1TwA_xvMzO-dm7uPYHzuDmEHBb0rKCFOH9Mo8pZxeVJLU8pLXl6bZFJISuWV0LW22TyQ9kleyG8UEoFl2JCPuboobM6H1z73qHPbB_RG9CYUKZdN7hgI2bYoo4-cSKGzJmstXFpxy6Dduxsv0LRRliDYenCsIQkgr7JVr4Yl-hHnxb0mH0n_bHcJzsG2oAHX3tKnq-vnua3-f3Dzd388j7XXFQxZ1yDYBQKXtY1UCYWJs0ZUM6YBEF5IzRdNAWTzDDOBc4qg7oENIuGLYTkU3K88R28ex0xRNXZoLFt011uDIqJmpYVKxKx3BC1dyF4NGrwtgP_rgqqVqWrdelq1aiqpVqXrljSHX0FQNDQGg-9tuFXXNViVpeJdrGhYfrsm0WvgrbYa2ysT6Woxtl_gj4B3NWaqw</recordid><startdate>1999</startdate><enddate>1999</enddate><creator>Nairn, K.M</creator><creator>Best, A.S</creator><creator>Newman, P.J</creator><creator>MacFarlane, D.R</creator><creator>Forsyth, M</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>1999</creationdate><title>Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte</title><author>Nairn, K.M ; Best, A.S ; Newman, P.J ; MacFarlane, D.R ; Forsyth, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-23ca620a13599a026bfa024a03228a603d6c0bd1282f2336e47fec5aefbd2b683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Properties of electrolytes: conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nairn, K.M</creatorcontrib><creatorcontrib>Best, A.S</creatorcontrib><creatorcontrib>Newman, P.J</creatorcontrib><creatorcontrib>MacFarlane, D.R</creatorcontrib><creatorcontrib>Forsyth, M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nairn, K.M</au><au>Best, A.S</au><au>Newman, P.J</au><au>MacFarlane, D.R</au><au>Forsyth, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte</atitle><jtitle>Solid state ionics</jtitle><date>1999</date><risdate>1999</risdate><volume>121</volume><issue>1</issue><spage>115</spage><epage>119</epage><pages>115-119</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><coden>SSIOD3</coden><abstract>Composite electrolytes of the lithium-ion-conducting ceramic Li
1.3Al
0.3Ti
1.7(PO
4)
3 and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, the composites are no more conductive than the pure polymer electrolyte. Exposing the samples to the vapour of solvents such as DMF, acetonitrile or water produces a significant increase in conductivity, over and beyond simple plasticization of the polymer. Pretreating the ceramic with a compatibilizing agent improves adhesion at the interface with the polymer, but decreases overall conductivity in the case investigated.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/S0167-2738(98)00537-2</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0167-2738 |
| ispartof | Solid state ionics, 1999, Vol.121 (1), p.115-119 |
| issn | 0167-2738 1872-7689 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26905721 |
| source | ScienceDirect Journals |
| subjects | Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Properties of electrolytes: conductivity |
| title | Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte |
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