Black Phosphorus: Fundamental Properties and Influence of Impurities Induced by Its Synthesis

Black phosphorus (BP) has been among the most widely explored materials in recent years because of its exceptional properties. A vapor transport method using tin and iodide as mineralizers was used to synthesize large crystals which can be used for fundamental physical characterization including ele...

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Bibliographic Details
Published in:ACS applied materials & interfaces 2022-08, Vol.14 (30), p.34867-34874
Main Authors: Antonatos, Nikolas, Šturala, Jiří, Mazánek, Vlastimil, Sedmidubský, David, Veselý, Martin, Růžička, Květoslav, Hejtmánek, Jiři, Levinsky, Petr, Sofer, Zdeněk
Format: Article
Language:English
Subjects:
Functional Inorganic Materials and Devices
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Summary:Black phosphorus (BP) has been among the most widely explored materials in recent years because of its exceptional properties. A vapor transport method using tin and iodide as mineralizers was used to synthesize large crystals which can be used for fundamental physical characterization including electrical and heat transport and heat capacity. This method is compared to other reported procedures (high-pressure crystal growth and mercury catalysis) which are broadly used and the most dominant procedures for the obtainment of bulk layered BP. In addition, we have investigated any possible impurities which could have been introduced by synthesis and their possible incorporation into BP and their influence on the physical properties of BP.
ISSN:1944-8244
1944-8252
DOI:10.1021/acsami.2c08714