Hidden Structural and Superconducting Phase Induced in Antiperovskite Arsenide SrPd3As

• Published in: Inorganic chemistry 2022-08, Vol.61 (31), p.12149-12154
• Main Authors: Iyo, Akira, Fujihisa, Hiroshi, Gotoh, Yoshito, Ishida, Shigeyuki, Ninomiya, Hiroki, Yoshida, Yoshiyuki, Eisaki, Hiroshi, Kawashima, Kenji
• Format: Article
• Language: English
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/acs.inorgchem.2c00960

Enriching the material variation often contributes to the progress of materials science. We have discovered for the first time antiperovskite arsenide SrPd3As and revealed a hidden structural and superconducting phase in Sr­(Pd1–x Pt x )3As. The Pd-rich samples (0 ≤ x ≤ 0.2) had the same noncentrosymmetric (NCS) tetragonal structure (a space group of I41 md) as SrPd3P. For the samples with 0.3 ≤ x ≤ 0.7, a centrosymmetric (CS) tetragonal structure (P4/nmm) identical to that of SrPt3P was found to appear, accompanied by superconductivity at a transition temperature (T c) up to 3.7 K. In the samples synthesized with Pt-rich nominal compositions (0.8 ≤ x ≤ 1.0), Sr2(Pd,Pt)8–y As1+y with an intergrowth structure (CS-orthorhombic with Cmcm) was crystallized. The phase diagram obtained for Sr­(Pd,Pt)3As was analogous to that of (Ca,Sr)­Pd3P in which superconductivity (T c ≥ 2 K) occurred in the CS phases induced by substitutions to the NCS phases. This study indicates the potential for further material variation expansion and the importance of elemental substitutions to reveal hidden phases in related antiperovskites.