Environmental friendly Polyacrylonitrile nanofiber mats encapsulated and coated with green algae mediated Titanium oxide nanoparticles for efficient oil spill adsorption

• Published in: Marine pollution bulletin 2022-09, Vol.182, p.113971-113971, Article 113971
• Main Authors: Poddar, Mrinal, Lakshmi, G.B.V.S., Sharma, Mahima, Chaudhary, Navneet, Nigam, Subhasha, Joshi, Monika, Solanki, Pratima R.
• Format: Article
• Language: English
• Subjects: Electrospinning; Green algae; Nanofibers; Oil adsorption; PAN; TiO2
• ISSN: 0025-326X; 1879-3363
• DOI: 10.1016/j.marpolbul.2022.113971

Oil spill causes extreme environmental damage, from aquatic life to seabirds, disrupting the entire ecosystem. Herein, we have synthesized high scale, economical and bio-compatible, green algae mediated Titanium oxide (TiO2) nanoparticles and Polyacrylonitrile (PAN) nanofiber mats. We have studied the effect of encapsulation and coating of TiO2 nanoparticles over nanofiber mats for highly efficient oil spill adsorption. TiO2 encapsulated and coated PAN (TECP) nanofibers showed a maximum of 62.34 g g−1 adsorption capacity of petroleum oil from the water surface. Moreover, the composite mats show maximum adsorption within 45 s for up to 5 repeated cycles. Further, it has been observed that the adsorption capacity has increased by increasing the weight of the composite nanofiber mats, which confirms its commercial applicability. Thus, this work provides rapid, large-scale, economical, bio-compatible, and highly effective adsorbents for oil spill cleaning and extraction over natural waterbodies. [Display omitted] •Fabrication of environment friendly and cost-effective TiO2 /PAN encapsulated, and coated mats•TECP nanofibers showed maximum of 62.34 g g−1 oil sorption capacity•Less than 10 % decrease in sorption capacity even after 5 cycles•Exponential increase in the adsorption capacity with increase in weight of nanofibers•Maximum adsorption efficiency attained under 45 s