How differences in the molecular structure of monohydroxy alcohols affect the tendency to crystallization

The tendency to crystallize was studied in the selected monohydroxy alcohols: 1-chloro-2-methyl-2-propanol, 1-chloro-2-propanol, 3-chloro-1-propanol, and 8-chloro-1-octanol. Performed calorimetric measurements have proved that the differences in structures of tested alcohols influence the tendency t...

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Published in:The European physical journal. E, Soft matter and biological physics Soft matter and biological physics, 2022-08, Vol.45 (8), p.64-64, Article 64
Main Authors: Łucak, Kinga, Kramarczyk, Daniel, Janus, Oliwia, Pawlus, Sebastian
Format: Article
Language:English
Subjects:
Biological and Medical Physics
Biophysics
Complex Fluids and Microfluidics
Complex Systems
Condensed matter physics
Crystallization
Elongation
Heating rate
Molecular structure
Nanotechnology
Octanol
Physics
Physics and Astronomy
Polymer Sciences
Regular Article - Soft Matter
Soft and Granular Matter
Soft Matter and Food
Surfaces and Interfaces
Thin Films
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container_title The European physical journal. E, Soft matter and biological physics
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creator Łucak, Kinga
Kramarczyk, Daniel
Janus, Oliwia
Pawlus, Sebastian
description The tendency to crystallize was studied in the selected monohydroxy alcohols: 1-chloro-2-methyl-2-propanol, 1-chloro-2-propanol, 3-chloro-1-propanol, and 8-chloro-1-octanol. Performed calorimetric measurements have proved that the differences in structures of tested alcohols influence the tendency to crystallization. At a sufficiently fast heating rate, no crystallization was observed in the case of 1-chloro-2-propanol and 3-chloro-1-propanol, contrary to other two alcohols. The obtained results suggest that elongation of the alkyl chain or adding a methyl group to the hydrocarbon backbone increases the susceptibility to crystallization. Graphical abstract
doi_str_mv 10.1140/epje/s10189-022-00215-0
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subjects Biological and Medical Physics
Biophysics
Complex Fluids and Microfluidics
Complex Systems
Condensed matter physics
Crystallization
Elongation
Heating rate
Molecular structure
Nanotechnology
Octanol
Physics
Physics and Astronomy
Polymer Sciences
Regular Article - Soft Matter
Soft and Granular Matter
Soft Matter and Food
Surfaces and Interfaces
Thin Films
title How differences in the molecular structure of monohydroxy alcohols affect the tendency to crystallization
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