Syndio-rich poly(methyl methacrylate) from the anionic polymerisation of methyl methacrylate in the presence of novel organoaluminium amides

New organoaluminium amide complexes have been designed and exploited as additives to produce syndio-rich poly(methyl methacrylate) (PMMA) in good yield and low polydispersity from the anionic polymerisation of methyl methacrylate (MMA) at 0 deg C.

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Bibliographic Details
Published in:Journal of materials chemistry 2001-11, Vol.11 (12), p.2915-2918
Main Authors: PERON, Guillaume L. N, PEACE, Richard J, HOLMES, Andrew B
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Description
Summary:New organoaluminium amide complexes have been designed and exploited as additives to produce syndio-rich poly(methyl methacrylate) (PMMA) in good yield and low polydispersity from the anionic polymerisation of methyl methacrylate (MMA) at 0 deg C.
ISSN:0959-9428
1364-5501
DOI:10.1039/b108091c