Surface modifications of a vulcanized rubber using corona discharge and ultraviolet radiation treatments

• Published in: Journal of materials science 2001-12, Vol.36 (24), p.5789-5799
• Main Authors: ROMERO-SANCHEZ, M. D, PASTOR-BLAS, M. M, MARTIN-MARTINEZ, J. M, ZHDAN, P. A, WATTS, J. F
• Format: Article
• Language: English
• Subjects: Applied sciences; Atomic beam spectroscopy; Atomic force microscopy; Butadiene; Coating, metallization, dyeing; Contact angle; Discharge; Exact sciences and technology; Infrared spectroscopy; Machinery and processing; Materials science; Microscopy; Migration; Morphology; Organic chemistry; Photoelectrons; Plastics; Polymer industry, paints, wood; Rubber; Scanning electron microscopy; Technology of polymers; Ultraviolet radiation; X ray photoelectron spectroscopy; Zinc stearate
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1023/A:1012999820592

Two different surface treatments have been applied to a synthetic vulcanized styrene-butadiene rubber (R1): corona discharge and UV treatment. Corona discharge treatment has been carried out on R1 rubber by varying the electrode-sample distance (2–4 mm), the duration (1 to 11 sec) and several parameters in the treatment of R1 rubber with UV treatment (lamp-sample distance between 1 and 5 cm, the duration between 30 sec and 5 min). The effects on both treatments on the surface of R1 were analyzed using contact angle measurements, ATR-IR spectroscopy, Scanning Electron Microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS) and Atomic Force Microscopy (AFM). A noticeable decrease in contact angles was observed on the R1 rubber by applying both treatments, although the modifications produced on the rubber surface were different. Corona discharge mainly affected the morphology of the R1 rubber surface whereas UV treatment mainly modified its chemistry. The migration of zinc stearate was only produced by UV treatment but not with corona discharge. Therefore, the UV treatment of R1 rubber was more aggressive, facilitating the migration of moieties from the bulk to the surface and producing oxygen moieties.