Ti3C2Tx MXene/urchin-like PANI hollow nanosphere composite for high performance flexible ammonia gas sensor

• Published in: Analytica chimica acta 2022-09, Vol.1225, p.340256-340256, Article 340256
• Main Authors: Cai, Yang, Wang, Yuwei, Wen, Xiangyu, Xiong, Jinlong, Song, Haoran, Li, Zhuo, Zu, Daoyuan, Shen, Yongming, Li, Changping
• Format: Article
• Language: English
• Subjects: Flexible; Food spoilage; NH3 sensor; Room temperature; Urchin-like PANI hollow Nanosphere
• ISSN: 0003-2670; 1873-4324
• DOI: 10.1016/j.aca.2022.340256

Ammonia (NH3) has been used as a typical indicator to monitor food spoilage, human health, and air quality. However, the development of flexible NH3 sensors with high response, excellent selectivity and low cost remains a huge challenge. Herein, a high performance NH3 sensor based on Ti3C2Tx MXene nanosheet/urchin-like PANI hollow nanosphere composite (MP) was fabricated through template method and in situ polymerization. The NH3 sensor is fabricated with no high cost electrodes through directly depositing this composite on flexible polyethylene terephthalate (PET) during polymerization. This optimized MP film sensor exhibits high response of 3.70 to 10 ppm NH3 at room temperature, which is 4.74-fold in comparison with urchin-like PANI hollow nanosphere (u-PANI). It also shows excellent selectivity, good repeatability, satisfactory flexibility, air stability and low detection limit of 30 ppb. The effective morphology control and heterojunction construction of MP composite are responsible for superior sensing performance. Moreover, the application of this film sensor in the monitoring of the spoilage process of fresh pork is demonstrated. This study offers a new strategy for fabricating high performance flexible room-temperature NH3 sensors, which may be scale fabrication and application in daily life. [Display omitted] •Synthesis of Ti3C2Tx/urchin-like PANI hollow nanosphere (MP) through template method and in situ polymerization.•The NH3 sensor based on MP possessed high response, low detection limit and excellent selectivity at room temperature.•The morphology control and heterojunction construction of MP were responsible for the superior sensing performance.•The application of MP film sensor in the monitoring of meat spoilage was demonstrated.