Effects of interface coating and nitride enhancing additive on properties of Hi-Nicalon SiC Fiber reinforced reaction-bonded silicon nitride composites

• Published in: Journal of materials science 2002, Vol.37 (1), p.141-150
• Main Authors: Bhatt, R. T, Hull, D. R, Eldridge, J. I, Babuder, R
• Format: Article
• Language: English
• Subjects: Aluminum; ambient temperature; Applied sciences; Bonding strength; Building materials. Ceramics. Glasses; Ceramic industries; Chemical industry and chemicals; Chemical reactions; Coated fibers; coating; coatings; Crack bridging; cracking; Diameters; Exact sciences and technology; Fiber composites; Fracture mechanics; Interfacial shear strength; Materials science; Nicalon (trademark); Nickel oxides; Porous media; Room temperature; Shear strength; Silicon carbide; Silicon nitride; Structural ceramics; Technical ceramics; Tensile properties; Thickness; Two dimensional composites
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1023/A:1013118514195

Strong and tough Hi-Nicalon SiC fiber reinforced reaction-bonded silicon nitride matrix composites (SiC/RBSN) have been fabricated by the fiber lay-up approach. Commercially available uncoated and PBN, PBN/Si-rich PBN, and BN/SiC coated SiC Hi-Nicalon fiber tows were used as reinforcement. The composites contained ∼24 vol% of aligned 14 μm diameter SiC fibers in a porous RBSN matrix. Both one- and two-dimensional composites were characterized. The effects of interface coating composition, and the nitridation enhancing additive, NiO, on the room temperature physical, tensile, and interfacial shear strength properties of SiC/RBSN matrix composites were evaluated. Results indicate that for all three coated fibers, the thickness of the coatings decreased from the outer periphery to the interior of the tows, and that from 10 to 30 percent of the fibers were not covered with the interface coating. In the uncoated regions, chemical reaction between the NiO additive and the SiC fiber occurs causing degradation of tensile properties of the composites. Among the three interface coating combinations investigated, the BN/SiC coated Hi-Nicalon SiC fiber reinforced RBSN matrix composite showed the least amount of uncoated regions and reasonably uniform interface coating thickness. The matrix cracking stress in SiC/RBSN composites was predicted using a fracture mechanics based crack bridging model.