Pd-Catalyzed Borylsilylative Cyclization of 1,6-Allenynes

A Pd-catalyzed borylsilylative cyclization of 1,6-allenynes with PhMe2SiBpin was developed. This method provides a practical and general method to afford the carbocycles and heterocycles bearing silyl and boryl groups with excellent regioselectivities and stereoselectivities in high to excellent yie...

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Published in:Organic letters 2022-09, Vol.24 (38), p.7021-7025
Main Authors: Zhang, Yinchao, Xu, Wenxiu, Gao, Tongtong, Guo, Mengjuan, Yang, Chun-Hua, Xie, Hua, Kong, Xiangtao, Yang, Zhantao, Chang, Junbiao
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cited_by cdi_FETCH-LOGICAL-a322t-3565f6d792b95ab31edecf4f76a6c916f68193e6c314551a4bf72cc82c65da2a3
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container_end_page 7025
container_issue 38
container_start_page 7021
container_title Organic letters
container_volume 24
creator Zhang, Yinchao
Xu, Wenxiu
Gao, Tongtong
Guo, Mengjuan
Yang, Chun-Hua
Xie, Hua
Kong, Xiangtao
Yang, Zhantao
Chang, Junbiao
description A Pd-catalyzed borylsilylative cyclization of 1,6-allenynes with PhMe2SiBpin was developed. This method provides a practical and general method to afford the carbocycles and heterocycles bearing silyl and boryl groups with excellent regioselectivities and stereoselectivities in high to excellent yields.
doi_str_mv 10.1021/acs.orglett.2c02878
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title Pd-Catalyzed Borylsilylative Cyclization of 1,6-Allenynes
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