Magnetite Metal–Organic Frameworks: Applications in Environmental Remediation of Heavy Metals, Organic Contaminants, and Other Pollutants

• Published in: Inorganic chemistry 2022-10, Vol.61 (40), p.15747-15783
• Main Authors: Taghavi, Reza, Rostamnia, Sadegh, Farajzadeh, Mustafa, Karimi-Maleh, Hassan, Wang, Jinghan, Kim, Dokyoon, Jang, Ho Won, Luque, Rafael, Varma, Rajender S., Shokouhimehr, Mohammadreza
• Format: Article
• Language: English
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/acs.inorgchem.2c01939

Due to the increasing environmental pollution caused by human activities, environmental remediation has become an important subject for humans and environmental safety. The quest for beneficial pathways to remove organic and inorganic contaminants has been the theme of considerable investigations in the past decade. The easy and quick separation made magnetic solid-phase extraction (MSPE) a popular method for the removal of different pollutants from the environment. Metal–organic frameworks (MOFs) are a class of porous materials best known for their ultrahigh porosity. Moreover, these materials can be easily modified with useful ligands and form various composites with varying characteristics, thus rendering them an ideal candidate as adsorbing agents for MSPE. Herein, research on MSPE, encompassing MOFs as sorbents and Fe3O4 as a magnetic component, is surveyed for environmental applications. Initially, assorted pollutants and their threats to human and environmental safety are introduced with a brief introduction to MOFs and MSPE. Subsequently, the deployment of magnetic MOFs (MMOFs) as sorbents for the removal of various organic and inorganic pollutants from the environment is deliberated, encompassing the outlooks and perspectives of this field.