Screening of microplastics in water and sludge lines of a drinking water treatment plant in Catalonia, Spain

• Published in: Water research (Oxford) 2022-10, Vol.225, p.119185-119185, Article 119185
• Main Authors: Dronjak, Lara, Exposito, Nora, Rovira, Joaquim, Florencio, Karin, Emiliano, Pere, Corzo, Beatriz, Schuhmacher, Marta, Valero, Fernando, Sierra, Jordi
• Format: Article
• Language: English
• Subjects: cellulose; Drinking water; filtration; Fourier transform infrared spectroscopy; hydrogen peroxide; ingestion; microplastics; oxidation; Plastic pollution; polyacrylonitrile; polyamides; polyesters; polyethylene; polypropylenes; polyurethanes; Removal ratios; seafoods; Sludge; Spain; water; water treatment; zinc chloride
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/j.watres.2022.119185

•MPs levels were 4.23 MPs/L and 0.075 MPs/L in influent and effluent, respectively.•Sludge (14 MP/g) and centrifugation water (194 MP/L) had high MPs levels, mainly fibers.•DWTP global removal rate of MPs in the studied DWTP was 98.3%.•In last DWTP steps MPs levels increase, this should be deeply studied. Microplastics (MPs) are emerging pollutants detected everywhere in the environment, with the potential to harm living organisms. The present study investigated the concentration, morphology, and composition of MPs, between 20 μm and 5 mm, in a drinking water treatment plant (DWTP) located close to Barcelona (Catalonia, NE Spain). The sampling included different units of the DWTP, from influent to effluent as well as sludge line. Sampling strategy, filtration, allows sampling of large volumes of water avoiding sample contamination, and during 8 h in order to increase the representativeness of MPs collected. The pre-treatment of the samples consisted of advanced oxidation with Fenton's reagent and hydrogen peroxide, followed by density separation of the particles with zinc chloride solution. Visual identification was performed with an optical and stereoscopic microscope with final Fourier-transform infrared spectroscopic (FTIR) confirmation. MPs were found in all DWTP samples, with concentrations from 4.23 ± 1.26 MPs/L to 0.075 ± 0.019 MPs/L in the influent and effluent of the plant, respectively. The overall removal efficiency of the plant was 98.3%. The most dominant morphology was fibers followed by fragments and films. Twenty-two different polymer types were identified and synthetic cellulose, polyester, polyamide, polypropylene, polyethylene, polyurethane, and polyacrylonitrile were the most common. Although MPs could be incorporated from the distribution network, MPs intake from drinking water from this DWTP was not an important route compared to fish and seafood ingestion.