Light-Driven Liquid Conveyors: Manipulating Liquid Mobility and Transporting Solids on Demand

• Published in: ACS nano 2022-10, Vol.16 (10), p.16353-16362
• Main Authors: Manabe, Kengo, Saito, Koichiro, Nakano, Miki, Ohzono, Takuya, Norikane, Yasuo
• Format: Article
• Language: English
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.2c05524

The intelligent transport of materials at interfaces is essential for a wide range of processes, including chemical microreactions, bioanalysis, and microfabrication. Both passive and active methods have been used to transport droplets, among which light-based techniques have attracted much attention because they are noncontact, safe, reversible, and controllable. However, conventional light-driven systems also involve challenges related to low transport ability and instability. Because of these shortcomings, technologies that can transport and manipulate droplets and microsolids on the same surface have yet to be realized. The present work demonstrates a light-driven system referred to as a liquid conveyor that enables the transport of both water droplets and microsolids. After the incorporation of an azobenzene-based molecular motor capable of undergoing photoisomerization into the surface liquid layer of this system, an isomerization gradient was induced by exposure to ultraviolet light emitting diodes that induced flow in this layer. Various parameters were optimized, including the concentration of the molecular motor compound, the light intensity, the viscosity of the liquid layer, and the droplet volume. This process eventually achieved the horizontal transport of droplets in any direction at varied rates. As a consequence of the limited heat buildup, the lack of droplet deformation, and extremely small contact angle hysteresis in this system, microsolids on droplets were also transported. This liquid conveyor is a promising platform for high-throughput omni-liquid/solid manipulation in the fields of biotechnology, chemistry, and mechanical engineering.