Synthesis and Characterisation of Branched Poly(ethylene terephthalate)

• Published in: Polymer international 1997-03, Vol.42 (3), p.267-275
• Main Authors: Rosu, Ruxandra F., Shanks, Robert A., Bhattacharya, Sati N.
• Format: Article
• Language: English
• Subjects: Applied sciences; branching; crystallinity; Exact sciences and technology; Organic polymers; PET; Physicochemistry of polymers; Polycondensation; Preparation, kinetics, thermodynamics, mechanism and catalysts; reaction rate; solid-state polymerisation; thermal behaviour
• ISSN: 0959-8103; 1097-0126
• DOI: 10.1002/(SICI)1097-0126(199703)42:3<267::AID-PI712>3.0.CO;2-Z

Branched poly(ethylene terephthalate)s (PET) were synthesised with a variety of molar masses and with a large range of degree of branching by introduction of mono‐, tri‐(glycerol) and tetra‐functional (pentaerythritol) comonomers to dimethyl terephthalate and ethylene glycol. The monofunctional alcohols, dodecanol and benzyl alcohol, were used as terminating agents to minimise gelation. The effect of various reaction parameters, such as percentage glycerol or pentaerythritol and polymerisation time, on limiting viscosity number [η] and weight average molar mass (Mw) were investigated. The thermal behaviour of branched PET was studied by differential scanning calorimetry; all samples showed a characteristic double endothermic melting peak and the glass transition temperature was not observed. Some branched PETs were subjected to solid‐state polymerisation to increase the molar mass of previously prepared branched polymers. The solid‐state polymerisation technique showed that the process not only promoted the molar mass but, more importantly, it increased the crystallinity of the polymer. Overall, the solid‐state reaction rate was governed by initial molar mass, crystallinity, reaction temperature and time. © of SCI.