Bulk nucleation and crystal growth in calcium tetra and digermanate glasses

Calcium tetragermanate and calcium digermanate glasses were prepared and studied with the aid of differential thermal analysis, X-ray diffraction and FTIR spectroscopy. The molar ratio of GeO 6 GeO 4 groups increases with the CaO GeO 2 molar ratio. A two steps crystallisation process was found: init...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the European Ceramic Society 1998, Vol.18 (11), p.1587-1591
Main Authors: Catauro, M., Laudisio, G.
Format: Article
Language:English
Subjects:
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Growth from solid phases (including multiphase diffusion and recrystallization)
Materials science
Methods of crystal growth
physics of crystal growth
Physics
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3
cites cdi_FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3
container_end_page 1591
container_issue 11
container_start_page 1587
container_title Journal of the European Ceramic Society
container_volume 18
creator Catauro, M.
Laudisio, G.
description Calcium tetragermanate and calcium digermanate glasses were prepared and studied with the aid of differential thermal analysis, X-ray diffraction and FTIR spectroscopy. The molar ratio of GeO 6 GeO 4 groups increases with the CaO GeO 2 molar ratio. A two steps crystallisation process was found: initially microcrystals are formed that at higher temperatures are transformed in well shaped crystals. An unidentified phase crystallises in both glasses. CaGe 2O 5 crystals also grow in calcium digermanate glass. The influence of the specific surface area of the glass sample and of a heat treatment of nucleation was pointed out. The activation energy for crystal growth in each glass was evaluated by a non isothermal method.
doi_str_mv 10.1016/S0955-2219(98)00079-X
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_27438509</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S095522199800079X</els_id><sourcerecordid>27438509</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3</originalsourceid><addsrcrecordid>eNqFkEtLAzEUhYMoWKs_QZiFiC5Gk8xMHivR4gsLLlToLtxJMjU6j5pklP57x7Z06-puvnMP50PomOALggm7fMGyKFJKiTyT4hxjzGU620EjIniWMiJnu2i0RfbRQQgfGBOOpRyhp5u-_kzaXtcWouvaBFqTaL8MEepk7ruf-J64NtFQa9c3SbTRw4oxbm59Ay1Em8xrCMGGQ7RXQR3s0eaO0dvd7evkIZ0-3z9OrqepzhiPqaWUsUyUtOSSMioYM5ATLAoDACWFSnAu84JywhmvTF5pYEQYzcuKF9hANkan678L3331NkTVuKBtXUNruz4oyvNMFFgOYLEGte9C8LZSC-8a8EtFsPpTp1bq1J8XJYVaqVOzIXeyKYAwLK88tNqFbZjmNOOYDtjVGrPD2G9nvQra2VZb47zVUZnO_VP0C35Wg0g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>27438509</pqid></control><display><type>article</type><title>Bulk nucleation and crystal growth in calcium tetra and digermanate glasses</title><source>Elsevier</source><creator>Catauro, M. ; Laudisio, G.</creator><contributor>WCA</contributor><creatorcontrib>Catauro, M. ; Laudisio, G. ; WCA</creatorcontrib><description>Calcium tetragermanate and calcium digermanate glasses were prepared and studied with the aid of differential thermal analysis, X-ray diffraction and FTIR spectroscopy. The molar ratio of GeO 6 GeO 4 groups increases with the CaO GeO 2 molar ratio. A two steps crystallisation process was found: initially microcrystals are formed that at higher temperatures are transformed in well shaped crystals. An unidentified phase crystallises in both glasses. CaGe 2O 5 crystals also grow in calcium digermanate glass. The influence of the specific surface area of the glass sample and of a heat treatment of nucleation was pointed out. The activation energy for crystal growth in each glass was evaluated by a non isothermal method.</description><identifier>ISSN: 0955-2219</identifier><identifier>EISSN: 1873-619X</identifier><identifier>DOI: 10.1016/S0955-2219(98)00079-X</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Growth from solid phases (including multiphase diffusion and recrystallization) ; Materials science ; Methods of crystal growth; physics of crystal growth ; Physics</subject><ispartof>Journal of the European Ceramic Society, 1998, Vol.18 (11), p.1587-1591</ispartof><rights>1998</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3</citedby><cites>FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=2423702$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><contributor>WCA</contributor><creatorcontrib>Catauro, M.</creatorcontrib><creatorcontrib>Laudisio, G.</creatorcontrib><title>Bulk nucleation and crystal growth in calcium tetra and digermanate glasses</title><title>Journal of the European Ceramic Society</title><description>Calcium tetragermanate and calcium digermanate glasses were prepared and studied with the aid of differential thermal analysis, X-ray diffraction and FTIR spectroscopy. The molar ratio of GeO 6 GeO 4 groups increases with the CaO GeO 2 molar ratio. A two steps crystallisation process was found: initially microcrystals are formed that at higher temperatures are transformed in well shaped crystals. An unidentified phase crystallises in both glasses. CaGe 2O 5 crystals also grow in calcium digermanate glass. The influence of the specific surface area of the glass sample and of a heat treatment of nucleation was pointed out. The activation energy for crystal growth in each glass was evaluated by a non isothermal method.</description><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Growth from solid phases (including multiphase diffusion and recrystallization)</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Physics</subject><issn>0955-2219</issn><issn>1873-619X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_QZiFiC5Gk8xMHivR4gsLLlToLtxJMjU6j5pklP57x7Z06-puvnMP50PomOALggm7fMGyKFJKiTyT4hxjzGU620EjIniWMiJnu2i0RfbRQQgfGBOOpRyhp5u-_kzaXtcWouvaBFqTaL8MEepk7ruf-J64NtFQa9c3SbTRw4oxbm59Ay1Em8xrCMGGQ7RXQR3s0eaO0dvd7evkIZ0-3z9OrqepzhiPqaWUsUyUtOSSMioYM5ATLAoDACWFSnAu84JywhmvTF5pYEQYzcuKF9hANkan678L3331NkTVuKBtXUNruz4oyvNMFFgOYLEGte9C8LZSC-8a8EtFsPpTp1bq1J8XJYVaqVOzIXeyKYAwLK88tNqFbZjmNOOYDtjVGrPD2G9nvQra2VZb47zVUZnO_VP0C35Wg0g</recordid><startdate>1998</startdate><enddate>1998</enddate><creator>Catauro, M.</creator><creator>Laudisio, G.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1998</creationdate><title>Bulk nucleation and crystal growth in calcium tetra and digermanate glasses</title><author>Catauro, M. ; Laudisio, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Growth from solid phases (including multiphase diffusion and recrystallization)</topic><topic>Materials science</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Catauro, M.</creatorcontrib><creatorcontrib>Laudisio, G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the European Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Catauro, M.</au><au>Laudisio, G.</au><au>WCA</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bulk nucleation and crystal growth in calcium tetra and digermanate glasses</atitle><jtitle>Journal of the European Ceramic Society</jtitle><date>1998</date><risdate>1998</risdate><volume>18</volume><issue>11</issue><spage>1587</spage><epage>1591</epage><pages>1587-1591</pages><issn>0955-2219</issn><eissn>1873-619X</eissn><abstract>Calcium tetragermanate and calcium digermanate glasses were prepared and studied with the aid of differential thermal analysis, X-ray diffraction and FTIR spectroscopy. The molar ratio of GeO 6 GeO 4 groups increases with the CaO GeO 2 molar ratio. A two steps crystallisation process was found: initially microcrystals are formed that at higher temperatures are transformed in well shaped crystals. An unidentified phase crystallises in both glasses. CaGe 2O 5 crystals also grow in calcium digermanate glass. The influence of the specific surface area of the glass sample and of a heat treatment of nucleation was pointed out. The activation energy for crystal growth in each glass was evaluated by a non isothermal method.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0955-2219(98)00079-X</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0955-2219
ispartof Journal of the European Ceramic Society, 1998, Vol.18 (11), p.1587-1591
issn 0955-2219
1873-619X
language eng
recordid cdi_proquest_miscellaneous_27438509
source Elsevier
subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Growth from solid phases (including multiphase diffusion and recrystallization)
Materials science
Methods of crystal growth
physics of crystal growth
Physics
title Bulk nucleation and crystal growth in calcium tetra and digermanate glasses
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T19%3A23%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bulk%20nucleation%20and%20crystal%20growth%20in%20calcium%20tetra%20and%20digermanate%20glasses&rft.jtitle=Journal%20of%20the%20European%20Ceramic%20Society&rft.au=Catauro,%20M.&rft.date=1998&rft.volume=18&rft.issue=11&rft.spage=1587&rft.epage=1591&rft.pages=1587-1591&rft.issn=0955-2219&rft.eissn=1873-619X&rft_id=info:doi/10.1016/S0955-2219(98)00079-X&rft_dat=%3Cproquest_cross%3E27438509%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c367t-e226638b2b79262866da41085daaab2af877945271767fd4fca618dc7bf750da3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=27438509&rft_id=info:pmid/&rfr_iscdi=true