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Selective Oxidation of Alcohols through Fe3 O4 @SiO2 /K2 CO3 -Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System

K2 CO3 /Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nano...

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Bibliographic Details
Published in:ChemistryOpen (Weinheim) 2022-12, Vol.11 (12), p.e202200172
Main Authors: Abbasi, Sepideh, Reza Naimi-Jamal, Mohammad, Javanshir, Shahrzad, Heydari, Akbar
Format: Article
Language:English
Online Access:Get full text
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Summary:K2 CO3 /Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nanoparticles and deep eutectic solvent offers a novel, green, reusable catalyst with easy separation. Also, the catalyst structure was well characterized using techniques such as FT-IR spectroscopy, XRD, SEM, TGA, BET, VSM, TEM, and energy-dispersive X-ray spectroscopy (EDS).K2 CO3 /Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nanoparticles and deep eutectic solvent offers a novel, green, reusable catalyst with easy separation. Also, the catalyst structure was well characterized using techniques such as FT-IR spectroscopy, XRD, SEM, TGA, BET, VSM, TEM, and energy-dispersive X-ray spectroscopy (EDS).
ISSN:2191-1363
2191-1363
DOI:10.1002/open.202200172