Facile synthesis of CuO/g-C3N4 nanolayer composites with superior catalytic reductive degradation behavior

• Published in: Chemosphere (Oxford) 2023-02, Vol.315, p.137711-137711, Article 137711
• Main Authors: Suresh, R., Karthikeyan, N.S., Gnanasekaran, Lalitha, Rajendran, Saravanan, Soto-Moscoso, Matias
• Format: Article
• Language: English
• Subjects: 4-Nitrophenol; Catalytic reduction; CuO/g-C3N4 nanocomposite; Methyl orange
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2022.137711

The cupric oxide (CuO) loaded graphitic carbon nitride (g-C3N4) nanocomposites (CuO/g-C3N4) were prepared by a facile calcination method. The formation of monoclinic CuO nanocrystals along with g-C3N4 was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopic analysis. X-ray photoelectron spectral (XPS) analysis further confirms the formation of CuO/g-C3N4. Distribution of CuO stone-like crystalline nanoparticles on g-C3N4 nanosheets was observed by transmission electron microscopic images. The influence of CuO loading on the optical property of g-C3N4 was determined by ultraviolet (UV)-visible absorption and photoluminescence (PL) spectral analysis. Band gap was decreased from 2.7 to 2.3 eV by the addition of CuO nanoparticles. The catalytic performance of the synthesized samples in 4-nitrophenol (4-NP) and methyl orange (MO) reduction was evaluated. The 5 wt% CuO/g-C3N4 showed 99.5% (7 min) and 99.7% (4 min) reduction efficiency for 4-NP and MO respectively. The 5 wt% CuO/g-C3N4 could become a potential catalyst in the chemical treatment of organic pollutants. [Display omitted] •CuO loaded g-C3N4 nanocomposites were prepared by one-step calcination method.•4-NP and MO catalytic reduction behavior of CuO/g-C3N4 and pure CuO is better than g-C3N4.•5 wt% CuO/g-C3N4 nanocomposite showed maximum catalytic efficiency and rate constant than other samples.