Unclonable fluorescence of MgO‐ZrO2:Tb3+ nanocomposite for versatile applications in data security, dermatoglyphics

• Published in: Luminescence (Chichester, England) England), 2023-03, Vol.38 (3), p.232-249
• Main Authors: Swathi, B. N., Krushna, B. R. Radha, Daruka Prasad, B., Sharma, S. C., Subramanian, Balanehru, Nagabhushana, H.
• Format: Article
• Language: English
• Subjects: anti‐counterfeiting; cheiloscopy; Colour; Dermatoglyphics; Fingerprints; Fluorescence; Forensic science; latent fingerprint; Low temperature; Magnesium oxide; Methods; nanocomposite; Nanocomposites; Photoluminescence; Photons; Reflectance; Ridges; Security; Terbium; Zirconium dioxide
• ISSN: 1522-7235; 1522-7243
• DOI: 10.1002/bio.4440

Latent fingerprints (LFPs) are one among the most important types of evidences at crime scenes because of the distinctiveness and tenacity of the friction ridges in fingerprints (FPs). Therefore, it is essential in forensic science to develop a reliable method to detect LFPs. Traditional detection methods still face a number of difficulties, such as limited sensitivity, low contrast, strong background, and complex processing stages. In this study, MgO‐ZrO2:Tb3+ (1–5 mol%) (MZ:Tb) nanocomposites (NCs) were prepared via a simple solution combustion (SC) method at low temperature. The photoluminescence (PL) investigation demonstrates that when excited at 379 nm, the produced NCs emits distinctive emission peaks of terbium ions (Tb3+). According to the photometric results, the NCs can be employed as warm light NCs and emit light in the green portion of the colour spectrum. The estimated optical band gap from diffuse reflectance spectra is found to be in the range 4.84–4.97 eV. Regardless of the type of surface being used, the optimized MgO‐ZrO2:Tb3+ (4 mol%) (MZ:4Tb) NCs has a strong ability to minimize background fluorescence interference. With high contrast LFP and I–V type of cheiloscopy, these NCs present a flexible fluorescent mark for the identification of levels 1–3 details in forensic investigation. MgO‐ZrO2:Tb3+ (1–5 mol%) nanocomposites were prepared via solution combustion method. Prepared samples were used for anti‐counterfeiting applications. Optimized composite was able to detect level 3 details with high contrast latent fingerprint (LFP). These samples were also useful for warm light phosphor and emits light in the green portion of the colour spectrum.