Phosphorus-nitrogen containing fire retardants for poly(butylene terephthalate)

Hexakis(phenylamino)cyclotriphosphazene, hexakis(phenoxy)cyclotriphosphazene, tris(o‐phenylenediamino)cyclotriphosphazene, tris(phenylene‐1,2‐dioxy)cyclotriphosphazene and tris(phenylene‐1‐amino‐2‐oxy)cyclotriphosphazene have been prepared and characterized by IR and NMR spectroscopy. Phospham, a cr...

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Published in:Polymer international 2000-10, Vol.49 (10), p.1095-1100
Main Authors: Levchik, Galina F, Grigoriev, Yury V, Balabanovich, Alexander I, Levchik, Sergei V, Klatt, Martin
Format: Article
Language:English
Subjects:
Applied sciences
Compounding ingredients
Exact sciences and technology
fire retardancy
Fireproof agents
phosphazene
poly(butylene terephthalate)
Polymer industry, paints, wood
Technology of polymers
thermogravimetry
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container_end_page 1100
container_issue 10
container_start_page 1095
container_title Polymer international
container_volume 49
creator Levchik, Galina F
Grigoriev, Yury V
Balabanovich, Alexander I
Levchik, Sergei V
Klatt, Martin
description Hexakis(phenylamino)cyclotriphosphazene, hexakis(phenoxy)cyclotriphosphazene, tris(o‐phenylenediamino)cyclotriphosphazene, tris(phenylene‐1,2‐dioxy)cyclotriphosphazene and tris(phenylene‐1‐amino‐2‐oxy)cyclotriphosphazene have been prepared and characterized by IR and NMR spectroscopy. Phospham, a crosslinked phosphazene imide (PN2H) n, was prepared by heating hexaminotricyclophosphazene under vacuum. Phosphorus oxynitride (PON) m which is likely to be a crosslinked oxyphosphazene was prepared by intense heating of urea, melamine and phosphoric acid. These phosphorus–nitrogen containing compounds added to poly(butylene terephthalate) (PBT) at 10–20 wt% provided increase of oxygen index (OI) from 22 to 29. In spite of relatively high OI only the V‐2 rating was observed in the UL94 test because of the flaming drip phenomenon. Phosphorus oxynitride was found to be an efficient char promoter for PBT. © 2000 Society of Chemical Industry
doi_str_mv 10.1002/1097-0126(200010)49:10<1095::AID-PI405>3.0.CO;2-B
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source Wiley-Blackwell Read & Publish Collection
subjects Applied sciences
Compounding ingredients
Exact sciences and technology
fire retardancy
Fireproof agents
phosphazene
poly(butylene terephthalate)
Polymer industry, paints, wood
Technology of polymers
thermogravimetry
title Phosphorus-nitrogen containing fire retardants for poly(butylene terephthalate)
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