Preparation of Sr2CeO4 blue phosphor by ultrasonic spray pyrolysis: effect of NH4NO3 addition

A blue emission Sr2CeO4 phosphor powder which has a one-dimensional structure was prepared from a nitrate starting solution by the ultrasonic spray pyrolysis process. To avoid the formation of hollow particles during spray pyrolysis, NH4NO3 was employed to change the mechanism of Sr2CeO4 formation f...

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Bibliographic Details
Published in:Journal of materials science 2002-07, Vol.37 (13), p.2721-2729
Main Authors: KANG, Myung-Jin, CHOI, Se-Young
Format: Article
Language:English
Subjects:
Ammonium nitrate
Cerium nitrate
Chemistry
Chromaticity
Colloidal state and disperse state
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...)
Emission
Exact sciences and technology
Excitation
General and physical chemistry
Heat treatment
Inorganic chemistry and origins of life
Materials science
Morphology
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Other solid inorganic materials
Particle size distribution
Phosphors
Photoluminescence
Physics
Powders
Preparations and properties
Spray pyrolysis
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Summary:A blue emission Sr2CeO4 phosphor powder which has a one-dimensional structure was prepared from a nitrate starting solution by the ultrasonic spray pyrolysis process. To avoid the formation of hollow particles during spray pyrolysis, NH4NO3 was employed to change the mechanism of Sr2CeO4 formation from droplets, containing Sr(NO3)2 and Ce(NO3)3 in the required stoichiometric ratio. The mean particle size of as-prepared particle increased from 0.19 to 1.52 μm with a change in the overall concentration of the starting solution from 0.005 to 1.5 M. No hollow particles or particle fragments were observed when the ratio of overall concentration of the starting solution to NH4NO3 was equal to 1 : 1. The particles that were as-prepared with NH4NO3 had spherical morphology and a narrow size distribution. The emission spectrum of post heat-treated particles showed a broad maximum at 470 nm and the CIE Chromaticity coordinates were x = 0.20 and y = 0.27. The decay time of Sr2CeO4 phosphor powder was 58 μs, which is a long excited-state life time compared with d-f transitions for the Ce3+ excited state.
ISSN:0022-2461
1573-4803
DOI:10.1023/A:1015873201247