Property modeling across transition temperatures in polymers: application to thermoplastic systems

The growing demand for virtual design of composite materials necessitates the development of comprehensive models relating the microstructure of the constituents to the macroscopic mechanical behavior. In this spirit, a new model was recently introduced that enables the computation of polymer stiffn...

Full description

Saved in:
Bibliographic Details
Published in:Journal of materials science 2002-03, Vol.37 (5), p.911-920
Main Authors: MAHIEUX, C. A, REIFSNIDER, K. L
Format: Article
Language:English
Subjects:
Applied sciences
Composite materials
Composites
Crystal structure
Crystallinity
Exact sciences and technology
Feasibility studies
Forms of application and semi-finished materials
Materials science
Mathematical models
Mechanical properties
Molecular weight
Organic chemistry
Parameters
Polymer industry, paints, wood
Polymer matrix composites
Statistical methods
Stiffness
Technology of polymers
Temperature
Thermoplastic resins
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The growing demand for virtual design of composite materials necessitates the development of comprehensive models relating the microstructure of the constituents to the macroscopic mechanical behavior. In this spirit, a new model was recently introduced that enables the computation of polymer stiffness over the entire range of use temperature (C. A. Mahieux and K. L. Reifsnider, Polymer42(7) (2001) 3281). A preliminary study stated the feasibility of the approach and the apparent possibility of applying this model to all polymers. The present study investigated the possibility of applying the model to some commercial thermoplastics: PMMA, PEEK, PPS and AS4/PPS composite. Cryogenic DMA were performed and the properties (crystallinity and molecular weight) of the composites were systematically varied. The model was applied to the different materials. The influence of the chemical nature, the molecular weight and the crystallinity content on the model input was carefully studied. The molecular nature and molecular weight were found to have little influence on the statistical parameters; the statistical parameter associated with the glass transition was found to vary linearly with crystalline content for the semi-crystalline samples. The model was found to successfully represent the behavior of all of the polymer based systems considered in the present study.
ISSN:0022-2461
1573-4803
DOI:10.1023/A:1014383427444