Structure of highly dispersed metals and oxides: exploring the capabilities of high-resolution electron microscopy

• Published in: Surface and interface analysis 2000-07, Vol.29 (7), p.411-421
• Main Authors: Bernal, S., Baker, R. T., Burrows, A., Calvino, J. J., Kiely, C. J., López-Cartes, C., Pérez-Omil, J. A., Rodríguez-Izquierdo, J. M.
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts: preparations and properties; Chemistry; Exact sciences and technology; General and physical chemistry; high-resolution electron microscopy; highly dispersed phases; image analysis; image simulation; neodymia/MgO; Pt/CeO2; Rh/CeO2; supported metal catalysts; supported oxide catalysts; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; VMgO catalysts
• ISSN: 0142-2421; 1096-9918
• DOI: 10.1002/1096-9918(200007)29:7<411::AID-SIA824>3.0.CO;2-F

The potential applicability of high‐resolution electron microscopy (HREM), in combination with image analysis and image simulation tools, to retrieve structural information from nanometre‐sized particles present in oxide‐supported metal and oxide catalysts is analysed. Specifically, the possibilities and limitations of this technique to determine features such as the size, morphology and chemical nature of the particles, their surface structure and their structural relationship with the support are considered through the discussion of several examples. The interpretation of a series of HREM images of Pt and Rh catalysts supported on cerium oxides after treatments under different redox environments illustrates the case of highly dispersed metals. In addition, the results obtained in this study provide an approximate picture of the evolution of metal– support interaction effects in this family of catalysts, which is closely related to three‐way catalysts (TWCs). The results of a nanostructural investigation of two catalyst systems, one consisting of MgO‐supported neodymia clusters and the second of vanadium– magnesium oxide also supported on MgO, provide the examples for supported oxide catalysts. These find application in oxidation reactions. For the former, the growth of neodymia in the form of rounded patches in a parallel orientation relationship with the support has been observed. For the vanadia‐containing catalysts, the formation of a weakly ordered MgV2O4 spinel surface phase on the MgO support crystallites, after exposure to typical reaction conditions in the oxidative dehydrogenation of propane, has been confirmed. The structural relationship at the spinel/MgO interface has also been established. Copyright © 2000 John Wiley & Sons, Ltd.