Tailoring confined CdS quantum dots in polysulfone membrane for efficiently durable performance in solar-driven wastewater remediating systems

• Published in: Journal of environmental management 2023-04, Vol.332, p.117351-117351, Article 117351
• Main Authors: Alsohaimi, Ibrahim Hotan, Alhumaimess, Mosaed S., Alzaid, Meshal, Essawy, Amr A., El-Aassar, M.R., Mohamed, Rasha M.K., Hassan, Hassan M.A.
• Format: Article
• Language: English
• Subjects: adsorption; aqueous solutions; CdS; environmental management; fluorometry; lighting; methylene blue; photocatalysis; Photodegradation; photolysis; Polymers; Polysulfone membrane; Quantum Dots; separation; Solar illumination; Sunlight; Wastewater
• ISSN: 0301-4797; 1095-8630
• DOI: 10.1016/j.jenvman.2023.117351

In this work, CdS quantum dots (QDs) were successfully confined in polysulfone membrane (PSM) to develop a photoactive membrane under solar illumination that was suited in wastewater remediating system. The CdS@PSM membranes were prepared using the nonsolvent induced phase separation (NIPS) approach. Optical measurements show the confinement of CdS quantum dots (QDs) in the PS matrix within the narrowest band gap (2.41 eV) at 5 wt% loading. PS has two strong emission peaks at 411 and 432 nm due to photoelectron-hole recombination on pure PSM's surface. Adding 1 wt% CdS QDs to PSM reduced the earlier peak and blue-shifted the latter, within the appearance of three emission peaks attributed to the near band-edge emission of confined CdS QDs. Overloading CdS reduced all emission peaks. Moreover, fluorimetric monitoring of •OH radicals indicates that PSM produces the least amount of photogenerated •OH radicals while CdS@PSM(5 wt%) achieved the highest productivity. Examining the developed membranes in detoxifying methylene blue (MB) from aqueous solution of natural pH 8.1 showed weak adsorption in dark over 90 min of contact while switching to solar illumination significantly photodegrade MB where the degradation efficiency starts from 49% for pure PSM to 79% for CdS@PSM(5 wt%). Influence of pH was found crucial on photodegradation efficacy. Acidic pH 3 showed the weakest photodegradation efficacy, while the alkaline pH 12 was 18.88 times more effective. The used CdS@PSM (5 wt%) was successfully photo-renovated by soaking in 10 mL of NaOH solution under Solar illumination for 15 min to be used in 4 consecutive photodegradation cycles with insignificant decrease in efficacy. These findings are promising and could lead to a high-efficiency, sustainable photocatalytic suite. [Display omitted] •CdS@PSM was successfully prepared with varied wt.% of CdS.•Fabricated membranes were tested in solar-driven wastewater remediation.•Incorporated CdS in the PSM resulted in enhanced optical properties and photocatalytic performance.•The CdS@PSM(5 wt%) membrane was found to be perform better.•The photocatalytic membranes showed durable photo-degradation performance.