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Synthesis and Physical Properties of a Perylene Diimide-Embedded Chiral Conjugated Macrocycle
Herein, we report the facile synthesis and properties of a chiral perylene diimide (PDI)-embedded conjugated macrocycle (cyclo[6]paraphenylene-1,7-perylene diimide, ) by Pd-catalyzed Suzuki coupling and a subsequent reductive aromatization reaction in two steps. The PDI-embedded conjugated macrocycl...
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| Published in: | Organic letters 2023-02, Vol.25 (7), p.1183-1187 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c235t-9fcf7e8772701839b12645405e63aab3a77cd51f39bedf4ee6537d3ba8f34fac3 |
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| cites | cdi_FETCH-LOGICAL-c235t-9fcf7e8772701839b12645405e63aab3a77cd51f39bedf4ee6537d3ba8f34fac3 |
| container_end_page | 1187 |
| container_issue | 7 |
| container_start_page | 1183 |
| container_title | Organic letters |
| container_volume | 25 |
| creator | Li, Along Zhang, Xinyu Wang, Shengda Wei, Kang Du, Pingwu |
| description | Herein, we report the facile synthesis and properties of a chiral perylene diimide (PDI)-embedded conjugated macrocycle (cyclo[6]paraphenylene-1,7-perylene diimide,
) by Pd-catalyzed Suzuki coupling and a subsequent reductive aromatization reaction in two steps. The PDI-embedded conjugated macrocycle showed a significant redshift (>110 nm for absorption) compared to the PDI molecule. Moreover, efficient resolution of chiral enantiomers with
was achieved by high-performance liquid chromatography, and their chiral properties were investigated by circular dichroism spectroscopy. The realization of
expands the scope of the precise synthesis of PDI-embedded chiral conjugated macrocycles and explores its unique physical properties. |
| doi_str_mv | 10.1021/acs.orglett.3c00152 |
| format | article |
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was achieved by high-performance liquid chromatography, and their chiral properties were investigated by circular dichroism spectroscopy. The realization of
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was achieved by high-performance liquid chromatography, and their chiral properties were investigated by circular dichroism spectroscopy. The realization of
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was achieved by high-performance liquid chromatography, and their chiral properties were investigated by circular dichroism spectroscopy. The realization of
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| language | eng |
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| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| title | Synthesis and Physical Properties of a Perylene Diimide-Embedded Chiral Conjugated Macrocycle |
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