Loading…

CDSD-1000, the high-temperature carbon dioxide spectroscopic databank

We present a high-temperature version, CDSD-1000, of the carbon dioxide spectroscopic databank. The databank contains the line parameters (positions, intensities, air- and self-broadened half-widths and coefficients of temperature dependence of air-broadened half-widths) of the four most abundant is...

Full description

Saved in:
Bibliographic Details
Published in:Journal of quantitative spectroscopy & radiative transfer 2003-11, Vol.82 (1), p.165-196
Main Authors: Tashkun, S.A., Perevalov, V.I., Teffo, J-L., Bykov, A.D., Lavrentieva, N.N.
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We present a high-temperature version, CDSD-1000, of the carbon dioxide spectroscopic databank. The databank contains the line parameters (positions, intensities, air- and self-broadened half-widths and coefficients of temperature dependence of air-broadened half-widths) of the four most abundant isotopic species of the carbon dioxide molecule. The reference temperature is T ref =1000 K and the intensity cutoff is I cut =10 −27 cm −1/ molecule cm −2 . More than 3 million lines covering the 260–8310, 418–2454, 394–4662, and 429– 2846 cm −1 spectral ranges for 12 C 16 O 2 , 13 C 16 O 2 , 12 C 16 O 18 O , and 12 C 16 O 17 O , respectively, are included in CDSD-1000. The databank has been generated within the framework of the method of effective operators and based on the global fittings of spectroscopic parameters (parameters of the effective Hamiltonians and effective dipole moment operators) to observed data collected from the literature. Line-by-line simulations of several low- and medium-resolution high-temperature ( T=800– 3000 K ) spectra have been performed in order to validate the databank. Comparisons of CDSD-1000 with other high-temperature databanks HITEMP, HITELOR, and EM2C are also given. CDSD-1000 is able to reproduce observed spectra in a more satisfactory way than the high-resolution databank HITEMP for temperatures higher than 1000 K . The databank is useful for studying high-temperature radiative properties of CO 2. CDSD-1000 is freely accessible via the Internet.
ISSN:0022-4073
1879-1352
DOI:10.1016/S0022-4073(03)00152-3