Alkali mass balance during the accelerated concrete prism test for alkali–aggregate reactivity

• Published in: Cement and concrete research 2003-08, Vol.33 (8), p.1147-1153
• Main Authors: Rivard, Patrice, Bérubé, Marc-André, Ollivier, Jean-Pierre, Ballivy, Gérard
• Format: Article
• Language: English
• Subjects: Alkalis; Alkali–aggregate reaction; Applied sciences; Buildings. Public works; Concretes. Mortars. Grouts; Exact sciences and technology; Expansion; General (composition, classification, performance, standards, patents, etc.); Leaching; Materials; Pore solution
• ISSN: 0008-8846; 1873-3948
• DOI: 10.1016/S0008-8846(03)00020-6

The alkali mass balance was calculated in concrete specimens submitted to the storage conditions of the Canadian standard CSA A23.2-14A concrete prism test for expansion due to alkali–aggregate reaction (AAR). The alkali concentration of both the concrete pore solution expressed under high pressure and the water below specimens in storage pails (bottom water) was measured. Measurements were conducted over a 1-year period, which corresponds to the length of the above test. Two reactive aggregates were tested [Potsdam sandstone (PO) and Spratt limestone (SP)]. Each aggregate was incorporated in two concrete mixtures ( mass concrete and structural concrete), for a total of four batches. Significant alkali leaching occurred at 38 °C while performing tests in high moisture storage conditions even though prisms were covered with plastic sleeves. After 52 weeks, the alkali loss ranged from 12% to 25% of the original Na 2O e content of the concrete, depending on the mixture proportioning and the aggregate type. After estimation of the proportion of alkalis fixed in cement hydrates, it appears that about 23% to 39% of the original alkalis released by the cement are quickly sorbed on aggregate surfaces or have rapidly migrated inside aggregate particles, which may have been incorporated with time in the AAR product. After 52 weeks at 38 °C, the pore solution alkalinity expressed from mass concrete made with PO was 250 mmol/l, whereas the alkalinity was 270 mmol/l in mass concrete incorporating SP. Since prisms of both mixtures were still expanding at 1 year, these alkalinity values are above the thresholds required for sustaining AAR in these concrete mixtures.