Ba4Ni3F14·H2O: a ferrimagnetic compound with a staircase kagomé lattice

A new crystalline fluoride Ba4Ni3F14·H2O was found to exhibit a rare S = 1 staircase kagomé lattice built by Ni2+ ions. Magnetic measurements indicate a ferrimagnetic transition at ∼28 K, while 1/3 plateau can be observed from the magnetization curve. We suggest that the hydrogen-bond interactions o...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-03, Vol.59 (26), p.3870-3873
Main Authors: Wang, Yanqi, Zhao, Zhiying, Cui, Meiyan, He, Zhangzhen
Format: Article
Language:English
Subjects:
Hydrogen bonds
Magnetic measurement
Magnetic properties
Magnetization curves
Online Access:Get full text
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Summary:A new crystalline fluoride Ba4Ni3F14·H2O was found to exhibit a rare S = 1 staircase kagomé lattice built by Ni2+ ions. Magnetic measurements indicate a ferrimagnetic transition at ∼28 K, while 1/3 plateau can be observed from the magnetization curve. We suggest that the hydrogen-bond interactions of O–H⋯F pathways may play an important role for magnetic properties of the system.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc06906g