Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix

We report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly­(dehydroalanine)-graft-poly­(ethylene glycol) (PDha-g-PE...

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Published in:ACS applied materials & interfaces 2023-05, Vol.15 (17), p.20833-20842
Main Authors: Costabel, Daniel, Nabiyan, Afshin, Chettri, Avinash, Jacobi, Franz, Heiland, Magdalena, Guthmuller, Julien, Kupfer, Stephan, Wächtler, Maria, Dietzek-Ivanšić, Benjamin, Streb, Carsten, Schacher, Felix H., Peneva, Kalina
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Energy, Environmental, and Catalysis Applications
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cited_by cdi_FETCH-LOGICAL-a260t-13053d5766664e99557e5733525a6516f0c4f078e6047f97609079779b85fc8d3
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container_end_page 20842
container_issue 17
container_start_page 20833
container_title ACS applied materials & interfaces
container_volume 15
creator Costabel, Daniel
Nabiyan, Afshin
Chettri, Avinash
Jacobi, Franz
Heiland, Magdalena
Guthmuller, Julien
Kupfer, Stephan
Wächtler, Maria
Dietzek-Ivanšić, Benjamin
Streb, Carsten
Schacher, Felix H.
Peneva, Kalina
description We report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly­(dehydroalanine)-graft-poly­(ethylene glycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF > 450 h–1) that are typical for noble-metal-containing systems. Excited-state absorption spectra reveal the formation of a long-lived triplet state of the PS in both aqueous and organic media. The system is a blueprint for developing noble-metal-free HER in water. Component optimization, e.g., by modification of the meso substituent of the PS and the composition of the HER catalyst, is further possible.
doi_str_mv 10.1021/acsami.2c18529
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subjects Energy, Environmental, and Catalysis Applications
title Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
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