Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study

• Published in: The journal of physical chemistry letters 2023-04, Vol.14 (15), p.3765-3776
• Main Authors: Huang, Jhih-Hong, Zhang, Fuyi, Shi, Yan-Pin, Cai, Jia-Rong, Chuang, Yu-Hsuan, Hu, Wei-Ping, Lee, Yin-Yu, Wang, Chia C.
• Format: Article
• Language: English
• Subjects: Physical Insights into the Biosphere, Atmosphere, and Space
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.3c00560

Although water may affect aqueous aerosol chemistry, how it intervenes in the formation of secondary organic aerosols (SOAs) at the molecular level remains elusive. Ozonolysis of limonene is one of the most important sources of indoor SOAs. Here, we report the valence electronic properties of limonene aerosols and SOAs derived from limonene ozonolysis (Lim-SOAs) via aerosol vacuum ultraviolet photoelectron spectroscopy, with a focus on the effects of water on Lim-SOAs. The first vertical ionization energy of limonene aerosols is measured to be 8.79 ± 0.07 eV. While water significantly increases the total photoelectron yield of Lim-SOAs, three photoelectron features attributable to Lim-SOAs each exhibit distinct dependence on the fraction of water in aerosols, implying that different formation pathways and molecular origins are involved in the formation of Lim-SOAs. Combined with density functional theory calculation and mass spectrometry measurements, this study reveals that water, particularly the water dimer, enhances the formation of Lim-SOAs by altering the ozonolysis energetics and pathways by intervening in its Criegee chemistry, acting as both a catalyst and a reactant. The atmospheric implication is discussed.