Synthesis of titanium dioxides in water-in-carbon dioxide microemulsion and their photocatalytic activity

• Published in: Materials letters 2003-06, Vol.57 (19), p.2975-2979
• Main Authors: Hong, Seong-Soo, Lee, Man Sig, Lee, Gun-Dae, Lim, Kwon Taek, Ha, Bae-Jin
• Format: Article
• Language: English
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Microemulsion; PFPE-NH 4 surfactant; Photocatalytic decomposition of p-nitrophenol; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Titania nanoparticles
• ISSN: 0167-577X; 1873-4979
• DOI: 10.1016/S0167-577X(02)01407-6

Titania nanoparticles were prepared by controlled hydrolysis of titanium tetraisopropoxide (TTIP) in water-in-carbon dioxide microemulsion using ammonium carboxylate perfluoropolyether (PFPE-NH 4) as a surfactant. The physical properties were examined by thermogravimetric-differential thermal analysis (TGA-DTA), X-ray diffraction (XRD) and transmission electron microscope (TEM). In addition, the photocatalytic decomposition of p-nitrophenol was also investigated using batch reactor in the presence of UV light. It is shown that the residual hydroxyl group and the organic compounds were completely removed in the calcining temperature from 250 to 450 °C and the amorphous phase transformed to anatase structure above 450 °C. The crystallinity and crystallite size of nanoparticles produced in water-in-carbon dioxide increased with an increase of W 0 ratio. In the photocatalytic decomposition of p-nitrophenol, the photocatalytic activity was mainly determined by the crystallite size of titania and the reaction rate increased with a decrease of crystallite size.