Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand

The synthesis and solid-state characterisation of the heterobimetallic rhodium( iii )/silver( i ) complex [Rh(2,2′-biphenyl)(CxP 2 )Cl]⊃Ag + is described, where CxP 2 is a trans -spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2023-04, Vol.52 (16), p.544-546
Main Authors: Emerson-King, Jack, Chaplin, Adrian B
Format: Article
Language:English
Subjects:
Chemistry
Ligands
Metathesis
Rhodium
Silver
Synthesis
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Summary:The synthesis and solid-state characterisation of the heterobimetallic rhodium( iii )/silver( i ) complex [Rh(2,2′-biphenyl)(CxP 2 )Cl]⊃Ag + is described, where CxP 2 is a trans -spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle. Structural elucidation of Cl→Ag + bonding using a cavitand-based ligand.
ISSN:1477-9226
1477-9234
DOI:10.1039/d3dt00567d