Atomic mechanisms of formation and structure relaxation of Fe83M17 (M: C, B, P) metallic glass

The individual characteristic properties of local atomic ordering of structure forming in Fe83M17 (M: C, B, P) metallic glass have been indicated by a computer simulation method. It is proved that carbon atoms 'prefer' to take up the interstitial positions in atomic configurations based on...

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Published in:Acta materialia 2003-05, Vol.51 (9), p.2665-2674
Main Authors: Evteev, A.V., Kosilov, A.T., Levtchenko, E.V.
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description The individual characteristic properties of local atomic ordering of structure forming in Fe83M17 (M: C, B, P) metallic glass have been indicated by a computer simulation method. It is proved that carbon atoms 'prefer' to take up the interstitial positions in atomic configurations based on a distorted octahedron and trigonal prism while boron atoms tend to occupy the centres of a distorted Archymedian antiprism. Phosphorus atoms are able to take up both the interstitial and the substitutional positions and the short-range ordering around them is mainly icosahedrical. The interrelationship between the atomic structure of Fe83M17 (M: C, B, P) amorphous metallic alloys and their vitrification ability has been determined.
doi_str_mv 10.1016/S1359-6454(03)00076-4
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title Atomic mechanisms of formation and structure relaxation of Fe83M17 (M: C, B, P) metallic glass
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