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Calculations of the transitions intensities in the optical spectra of Dy3+:LiYF4
Optical spectra of Dy3+:LiYF4 (Dy3+:YLF) single crystal were analyzed using Judd-Ofelt theory and discrete variational multielectron method (DVME). Oscillator strengths (OS) of transitions up to 39 000 cm-1 in the absorption spectrum, branching ratios and nonradiative transition rates were calculate...
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Published in: | Journal of alloys and compounds 2004-07, Vol.374 (1-2), p.63-68 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Optical spectra of Dy3+:LiYF4 (Dy3+:YLF) single crystal were analyzed using Judd-Ofelt theory and discrete variational multielectron method (DVME). Oscillator strengths (OS) of transitions up to 39 000 cm-1 in the absorption spectrum, branching ratios and nonradiative transition rates were calculated; assignment of the absorption transitions was given. A good agreement between calculated and experimental values of branching ratios for transitions from quartet 4F(3)9/2 to the low-lying sextet levels is demonstrated. Ab initio calculations of OS were performed. |
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ISSN: | 0925-8388 |
DOI: | 10.1016/j.jallcom.2003.11.142 |