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Calculations of the transitions intensities in the optical spectra of Dy3+:LiYF4

Optical spectra of Dy3+:LiYF4 (Dy3+:YLF) single crystal were analyzed using Judd-Ofelt theory and discrete variational multielectron method (DVME). Oscillator strengths (OS) of transitions up to 39 000 cm-1 in the absorption spectrum, branching ratios and nonradiative transition rates were calculate...

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Bibliographic Details
Published in:Journal of alloys and compounds 2004-07, Vol.374 (1-2), p.63-68
Main Authors: Brik, M.G., Ishii, T., Tkachuk, A.M., Ivanova, S.E., Razumova, I.K.
Format: Article
Language:English
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Summary:Optical spectra of Dy3+:LiYF4 (Dy3+:YLF) single crystal were analyzed using Judd-Ofelt theory and discrete variational multielectron method (DVME). Oscillator strengths (OS) of transitions up to 39 000 cm-1 in the absorption spectrum, branching ratios and nonradiative transition rates were calculated; assignment of the absorption transitions was given. A good agreement between calculated and experimental values of branching ratios for transitions from quartet 4F(3)9/2 to the low-lying sextet levels is demonstrated. Ab initio calculations of OS were performed.
ISSN:0925-8388
DOI:10.1016/j.jallcom.2003.11.142