Preparation of paramagnetic ferroferric oxide-calcined layered double hydroxide core–shell adsorbent for selective removal of anionic pollutants

• Published in: Journal of colloid and interface science 2023-09, Vol.645, p.319-328
• Main Authors: Tian, Xinru, Hao, Zewei, Wang, Can, Dong, Jianghong, Wang, Lina, Ma, Li, Gao, Yuanzhe, Han, Zhan-Gang, Zhang, Ruikang
• Format: Article
• Language: English
• Subjects: Adsorption; Core–shell; Fe3O4@cLDH; LDHs; Paramagnetism
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2023.04.151

A paramagnetic ferroferric oxide-calcined layered double hydroxide core–shell adsorbent was prepared with high selectivity to anionic pollutions. [Display omitted] •Fe3O4@cLDH core–shell adsorbent was prepared by the calcination of PB@LDH.•Fe3O4@cLDH adsorbent exhibits high anionic dye selectivity.•The paramagnetic Fe3O4@cLDH can be easily collected by a magnet.•The adsorption capability is affected by the pH and soluble CO2 in aqueous solution. Adsorption is one of the most common methods of pollution treatment. The selectivity for pollutants and recyclability of adsorbents are crucial to reduce the treatment cost. Layered double hydroxide (LDH) materials are one type of adsorbent with poor recyclability. Prussian blue (PB) is a sturdy and inexpensive metal–organic framework material that can be used as the precursor for synthesizing paramagnetic ferroferric oxide (Fe3O4). It is intriguing to build some reusable adsorbents with magnetic separation by integrating LDH and PB. In this work, paramagnetic Fe3O4-calcined LDH (Fe3O4@cLDH) core–shell adsorbent was designed and prepared by the calcination of PB-ZnAl layered double hydroxide (PB@LDH) core–shell precursor, which exhibits high anionic dyes selectivity in wastewater solutions. The paramagnetism and adsorption capability of Fe3O4@cLDH come from the Fe3O4 core and calcined ZnAl-LDH shell, respectively. Fe3O4@cLDH shows an adsorption capacity of 230 mg g−1 for acid orange and a high selectivity for anionic dyes in cation–anion mixed dye solutions. The regeneration process indicates that the high selectivity for anions is related to the specific hydration recovery process of ZnAl-LDH. The synergistic effect of the paramagnetic Fe3O4 core and calcined ZnAl-LDH shell makes Fe3O4@cLDH an excellent magnetic separation adsorbent with high selectivity to anions.