Effect of drying rate on mesoporous silica morphology templated from PEO-PPO-PEO block copolymer assemblies

The authors have shown that the rapid drying process of the nanocomplex of silicate and pluronics is favorable for the formation of closed nanopores, where the enclosure of the pores is promoted due to the solidification of silica prior to the formation of the liquid crystalline phase of pluronics m...

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Published in:Journal of materials science 2004-06, Vol.39 (12), p.4045-4047
Main Authors: PEI, L, KURUMADA, K.-I, TANIGAKI, M, HIRO, M, SUSA, K
Format: Article
Language:English
Subjects:
Block copolymers
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Materials science
Morphology
Porous materials
Silicon dioxide
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creator PEI, L
KURUMADA, K.-I
TANIGAKI, M
HIRO, M
SUSA, K
description The authors have shown that the rapid drying process of the nanocomplex of silicate and pluronics is favorable for the formation of closed nanopores, where the enclosure of the pores is promoted due to the solidification of silica prior to the formation of the liquid crystalline phase of pluronics molecular assemblies Here, we report the effect of drying rate on the morphology of mesoporous silicas templated from the pluronic triblock copolymer aggregates, and the formation of closed pores in the mesoscopic structure of the silica.
doi_str_mv 10.1023/B:JMSC.0000031492.71835.2b
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subjects Block copolymers
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Materials science
Morphology
Porous materials
Silicon dioxide
title Effect of drying rate on mesoporous silica morphology templated from PEO-PPO-PEO block copolymer assemblies
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